A new mononuclear hydrazone-based aluminum complex as a catalyst for solvent-free CO2 cycloaddition reaction

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00637927" target="_blank" >RIV/68378271:_____/25:00637927 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.ica.2025.122839" target="_blank" >https://doi.org/10.1016/j.ica.2025.122839</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2025.122839" target="_blank" >10.1016/j.ica.2025.122839</a>

Result language
angličtina
Original language name
A new mononuclear hydrazone-based aluminum complex as a catalyst for solvent-free CO2 cycloaddition reaction
Original language description
Recently, due to increasing concerns over carbon dioxide emissions and their impact on the environment, the study and conversion of it into valuable products have been of great interest. In general, aluminum-based complexes can be a good choice for CO2 cycloaddition reactions due to their strong Lewis acidity. Hence, a mononuclear aluminum complex [AlHL′(H2O)3](H2O)2Cl containing hydrazonic based ligand (sodium 4-hydroxy-3-{[2-(pyridine-4-carbonyl)hydrazinylidene]methyl}benzene-1-sulfonate) was synthesized and identified by FT-IR, 1H NMR, XRD and single-crystal X-ray crystallography.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
<a href="/en/project/LM2023051" target="_blank" >LM2023051: Research infrastructure CzechNanoLab</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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