A Copper(I)-Arene Complex With an Unsupported eta(6) Interaction

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21230%2F15%3A00226455" target="_blank" >RIV/68407700:21230/15:00226455 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/anie.201410948" target="_blank" >http://dx.doi.org/10.1002/anie.201410948</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201410948" target="_blank" >10.1002/anie.201410948</a>

Result language
angličtina
Original language name
A Copper(I)-Arene Complex With an Unsupported eta(6) Interaction
Original language description
Addition of PR3 (R=Ph or OPh) to [Cu((2)-Me6C6)(2)][PF6] results in the formation of [((6)-Me6C6)Cu(PR3)][PF6], the first copper-arene complexes to feature an unsupported (6) arene interaction. A DFT analysis reveals that the preference for the (6) binding mode is enforced by the steric clash between the methyl groups of the arene ligand and the phenyl rings of the phosphine co-ligand.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/EE2.3.30.0034" target="_blank" >EE2.3.30.0034: Support of inter-sectoral mobility and quality enhancement of research teams at Czech Technical University in Prague</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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