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Preparation and Potential Application of 2-(Indol-2-yl)-3,1-benzoxazin-4-ones

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F12%3A43868090" target="_blank" >RIV/70883521:28110/12:43868090 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Preparation and Potential Application of 2-(Indol-2-yl)-3,1-benzoxazin-4-ones

  • Original language description

    This paper describes work concerning the preparation of novel benzoxazinones substituted with indole moiety by cyclodehydration of appropriate 2-(indol-2-carboxamido)benzoic acids. A novel route to these acids utilising Fischer indole synthesis has beenalso established. The Fischer reaction precursors were readily obtained from 4 hydroxyquinolin 2-ones by two-step oxidation process. All compounds were characterized by available methods of structural analysis. The original purpose of this work was to prepare a series of title compounds for future testing as ultraviolet absorbers and as additives for the stabilization of polymers. Benzoxazinones can also be useful electrophilic reagents for the synthesis of some biologically active substances. In summary, a novel entry to direct construction of 2-(indol-2-yl)-3,1-benzoxazin-4-one skeleton based on Fischer indole reaction and subsequent dehydration was developed and allows the preparation of a wide variety of substituted benzoxazinones.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Plasty a kaučuk

  • ISSN

    0322-7340

  • e-ISSN

  • Volume of the periodical

    XLIX

  • Issue of the periodical within the volume

    49-Speciál

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    6

  • Pages from-to

    42-47

  • UT code for WoS article

  • EID of the result in the Scopus database