Nesymetrické multitopické ligandy pro kooperativitu kov-kov a kov-ligand

Název projektu anglicky
Dissymmetric multitopic ligands for metal-metal and metal-ligand cooperativity
Anotace anglicky
This project deals with the coordination and organometallic chemistry of guanidinates, biguanides and chelating amino-imides, which complexate two or more (semi)metal centers to form heterometallic compounds. The central atoms are connected through the ligand core, via a conjugated system of pi-bonds, or via aromatic azametalla-cycles. The major part of the project is focused to comparison of symmetric and dissymmetric structures, where the metal atom is coordinated to different functional groups. The structure and redox-active behavior of these compounds will be monitored in connection with interesting reactivity towards small molecules such as carbon dioxide, dihydrogen, etc. The catalytic activity will be tested also on model (co)polymerization and reduction reactions. As part of the study of the synergistic behavior of two or more metals in one molecule is the reactivity of compounds containing low-valent main group metals together with a transition metal. This could lead to more effective charge transfer, oxidative additions, and mainly reductive eliminations.

Kategorie VaV
ZV - Základní výzkum
OECD FORD - hlavní obor
10402 - Inorganic and nuclear chemistry
OECD FORD - vedlejší obor
10401 - Organic chemistry
OECD FORD - další vedlejší obor
—
CEP - odpovídající obory <br>(dle <a href="http://www.vyzkum.cz/storage/att/E6EF7938F0E854BAE520AC119FB22E8D/Prevodnik_oboru_Frascati.pdf">převodníku</a>)
CA - Anorganická chemie<br>CC - Organická chemie<br>CH - Jaderná a kvantová chemie, fotochemie

Důvěrnost údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Systémové označení dodávky dat
CEP25-GA0-GA-R
Datum dodání záznamu
7. 3. 2025

Podobné projekty(10)