Disociace molekulárního dusíku

Název projektu anglicky
Splitting of molecular nitrogen
Anotace anglicky
The project aims to prove the possibility of N2 activation by its splitting over a new type of active sites – distant binuclear cationic sites, and to employ this activated nitrogen for the synthesis of nitrogen-containing compounds such as NH3 or NO/NO2. For this purpose, distant binuclear cationic sites capable of the 2+/5+ redox cycle will be prepared and stabilized in the aluminosilicate matrix of the ferrierite zeolite, which allows the stabilization of two cations in opposite cationic sites at the distance of 0.75 nm essential for the cooperation of two cations in the six-electron process of N2 splitting. Formation and structure of binuclear cationic sites in zeolite matrix, as well as splitting of N2 over these sites, will be monitored by a multi-spectroscopic approach (FTIR, UV-Vis, ss-NMR) supported by DFT. Interaction of O2 and H2 with the split N2 will be studied by FTIR spectroscopy of products adsorbed in the zeolite, further the evolution and presence of products in the gas phase will be studied by through-flow experiments monitored by FTIR, GC and mass spectrometry.

Kategorie VaV
ZV - Základní výzkum
OECD FORD - hlavní obor
10403 - Physical chemistry
OECD FORD - vedlejší obor
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OECD FORD - další vedlejší obor
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CEP - odpovídající obory <br>(dle <a href="http://www.vyzkum.cz/storage/att/E6EF7938F0E854BAE520AC119FB22E8D/Prevodnik_oboru_Frascati.pdf">převodníku</a>)
CF - Fyzikální chemie a teoretická chemie

Důvěrnost údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Systémové označení dodávky dat
CEP24-GA0-GX-R
Datum dodání záznamu
19. 2. 2024

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