Raman spectroscopy of hydrogen-arsenate group (AsO3OH) in solid-state compounds: cobalt mineral phase burgessite Co2(H2O)4(AsO3OH)2 .H2O

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00023272%3A_____%2F11%3A%230001569" target="_blank" >RIV/00023272:_____/11:#0001569 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/jrs.2675" target="_blank" >http://dx.doi.org/10.1002/jrs.2675</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/jrs.2675" target="_blank" >10.1002/jrs.2675</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Raman spectroscopy of hydrogen-arsenate group (AsO3OH) in solid-state compounds: cobalt mineral phase burgessite Co2(H2O)4(AsO3OH)2 .H2O

Popis výsledku v původním jazyce

Raman spectrum of burgessite, Co2(H2O)4[AsO3OH]2. H2O, was studied, interpreted and compared with its infrared spectrum. The stretching and bending vibrations of (AsO3) and As-OH units, as well as the stretching, bending and libration modes of water molecules and hydroxyl ions were assigned. The range of O-H ...O hydrogen bond lengths was inferred from the Raman and infrared spectra of burgessite. The presence of (AsO3OH)2- units in the crystal structure of burgessite was proved, which is in agreement with its recently solved crystal structure. Raman and infrared spectra of erythrite inferred from the RRUFF database are used for comparison.

Název v anglickém jazyce

Raman spectroscopy of hydrogen-arsenate group (AsO3OH) in solid-state compounds: cobalt mineral phase burgessite Co2(H2O)4(AsO3OH)2 .H2O

Popis výsledku anglicky

Raman spectrum of burgessite, Co2(H2O)4[AsO3OH]2. H2O, was studied, interpreted and compared with its infrared spectrum. The stretching and bending vibrations of (AsO3) and As-OH units, as well as the stretching, bending and libration modes of water molecules and hydroxyl ions were assigned. The range of O-H ...O hydrogen bond lengths was inferred from the Raman and infrared spectra of burgessite. The presence of (AsO3OH)2- units in the crystal structure of burgessite was proved, which is in agreement with its recently solved crystal structure. Raman and infrared spectra of erythrite inferred from the RRUFF database are used for comparison.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

DB - Geologie a mineralogie

OECD FORD obor

—

Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Raman Spectroscopy

ISSN

0377-0486

e-ISSN

—

Svazek periodika

42

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

5

Strana od-do

214-218

Kód UT WoS článku

000288543000016

EID výsledku v databázi Scopus

—