Extreme PGE concentrations in lower Cambrian acid tuff layer from the Kunyang phosphate deposit, Yunnan Province, South China ? possible PGE source for lower Cambrian Mo-Ni-polyelement ore beds

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00025798%3A_____%2F10%3A00000143" target="_blank" >RIV/00025798:_____/10:00000143 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Extreme PGE concentrations in lower Cambrian acid tuff layer from the Kunyang phosphate deposit, Yunnan Province, South China ? possible PGE source for lower Cambrian Mo-Ni-polyelement ore beds

Popis výsledku v původním jazyce

A study of the PGE distribution in various lowermost Cambrian rock types of the Kunyang phosphate deposit in South China revealed surprisingly the highest PGE concentrations (434 ppb Pt, 142 ppb Pd, 57.97ppb Rh, < 1 ppb Ru and 0,14 ppb Ir) in a whole rock sample of acid tuff. The clay-quartz fraction of the tuff revealed elevated Ru and Ir concentrations but a depletion in Pt, Pd and Rh relative to the whole rock. LA-ICPMS analyses of pyrite and yielded comparatively high Ni and in some grains also elevated Re and Pd concentrations. It is very likely that the PGE are in part bound to submicroscopic inclusions in pyrite and/or intermetallic phases bound to the clay fraction. Our observations are consisten with diagenetic metal enrichment. Similar anomalously PGE-enriched acid tuffs could have played an important role in the origin of the slightly younger Mo-Ni-PGE phosphatic and sulfidic black shales in the Yangtze Platform.

Název v anglickém jazyce

Extreme PGE concentrations in lower Cambrian acid tuff layer from the Kunyang phosphate deposit, Yunnan Province, South China ? possible PGE source for lower Cambrian Mo-Ni-polyelement ore beds

Popis výsledku anglicky

A study of the PGE distribution in various lowermost Cambrian rock types of the Kunyang phosphate deposit in South China revealed surprisingly the highest PGE concentrations (434 ppb Pt, 142 ppb Pd, 57.97ppb Rh, < 1 ppb Ru and 0,14 ppb Ir) in a whole rock sample of acid tuff. The clay-quartz fraction of the tuff revealed elevated Ru and Ir concentrations but a depletion in Pt, Pd and Rh relative to the whole rock. LA-ICPMS analyses of pyrite and yielded comparatively high Ni and in some grains also elevated Re and Pd concentrations. It is very likely that the PGE are in part bound to submicroscopic inclusions in pyrite and/or intermetallic phases bound to the clay fraction. Our observations are consisten with diagenetic metal enrichment. Similar anomalously PGE-enriched acid tuffs could have played an important role in the origin of the slightly younger Mo-Ni-PGE phosphatic and sulfidic black shales in the Yangtze Platform.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

DD - Geochemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Economic Geology

ISSN

0361-0128

e-ISSN

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Svazek periodika

105

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

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Kód UT WoS článku

000285177600001

EID výsledku v databázi Scopus

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