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Viteite, Pd5InAs, a new mineral from the Monchetundra layered intrusion, Kola Peninsula, Russia

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00025798%3A_____%2F20%3A00000098" target="_blank" >RIV/00025798:_____/20:00000098 - isvavai.cz</a>

  • Výsledek na webu

    <a href="https://www.mineralogicalassociation.ca/the-canadian-mineralogist/" target="_blank" >https://www.mineralogicalassociation.ca/the-canadian-mineralogist/</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3749/canim.1900080" target="_blank" >10.3749/canim.1900080</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Viteite, Pd5InAs, a new mineral from the Monchetundra layered intrusion, Kola Peninsula, Russia

  • Popis výsledku v původním jazyce

    Viteite, Pd5InAs, is a new mineral discovered in the Monchetundra layered intrusion, Kola Peninsula, Russia. It forms euhedral grains about 0.5 to 10 micrometer in size intergrown with irarsite (IrAsS), hollingworthite (RhAsS), zvyagintsevite (Pd3Pb), Au-Ag alloys, and tulameenite (Pt2CuFe), that are replaced by Pt-Pd-Fe-Cu alloys and Pt-Pd-Fe-Cu oxygenated compounds, all of which are embedded in chalcocite, goethite, and covellite. Viteite is brittle and has a metallic luster. In plane-polarized light, viteite is bright pinkish-white. The mineral is weakly anisotropic with rotation tints blue to pinkish brown; it exhibits no internal reflections. Reflectance values of viteite in air (R1, R2 in percent) are 55.7, 54.0 at 470 nm; 59.2, 58.4 at 546 nm; 60.0, 60.4 at 589 nm; and 60.0, 62.6 at 650 nm. Eight electron-microprobe analyses of viteite give an average composition of Pd 71.90, Pt 1.60, Fe 0.98, Cu 0.59, In 11.48, Hg 1.42, Pb 0.40, As 10.70, total 99.07 wt.percent, corresponding to the empirical formula (Pd4.92Pt0.06)sigma4.98(In0.73Fe0.12Cu0.07Hg0.05Pb0.01)sigma0.98As1.04 based on 7 atoms; the average of 12 analyses of its synthetic analogue is: Pd 73.72, In 16.37, As 9.80, total 99.90 wt.percent, corresponding to Pd5.02In1.03As0.95. The density, calculated on the basis of the empirical formula, is 10.78 g/cm3. The mineral is tetragonal, space group P4/mmm, with a 3.98600(3), c 6.98385(8) angstroem, V 110.961(2) angstroem3, and Z = 1. The crystal structure of synthetic Pd5InAs was solved and refined using powder X-ray-diffraction data from synthetic Pd5InAs. Viteite crystallizes with the Pd5TlAs structure type. The strongest lines in the X-ray powder diffraction pattern of synthetic Pd5InAs [d in angstroem (I) (hkl)] are: 2.3281(45)(003), 2.1932(100)(112), 1.9928(33)(020), 1.2515(17)(115), 1.1857(25)(132). The mineral is named for the Vite river, which flows near the Monchetundra intrusion.

  • Název v anglickém jazyce

    Viteite, Pd5InAs, a new mineral from the Monchetundra layered intrusion, Kola Peninsula, Russia

  • Popis výsledku anglicky

    Viteite, Pd5InAs, is a new mineral discovered in the Monchetundra layered intrusion, Kola Peninsula, Russia. It forms euhedral grains about 0.5 to 10 micrometer in size intergrown with irarsite (IrAsS), hollingworthite (RhAsS), zvyagintsevite (Pd3Pb), Au-Ag alloys, and tulameenite (Pt2CuFe), that are replaced by Pt-Pd-Fe-Cu alloys and Pt-Pd-Fe-Cu oxygenated compounds, all of which are embedded in chalcocite, goethite, and covellite. Viteite is brittle and has a metallic luster. In plane-polarized light, viteite is bright pinkish-white. The mineral is weakly anisotropic with rotation tints blue to pinkish brown; it exhibits no internal reflections. Reflectance values of viteite in air (R1, R2 in percent) are 55.7, 54.0 at 470 nm; 59.2, 58.4 at 546 nm; 60.0, 60.4 at 589 nm; and 60.0, 62.6 at 650 nm. Eight electron-microprobe analyses of viteite give an average composition of Pd 71.90, Pt 1.60, Fe 0.98, Cu 0.59, In 11.48, Hg 1.42, Pb 0.40, As 10.70, total 99.07 wt.percent, corresponding to the empirical formula (Pd4.92Pt0.06)sigma4.98(In0.73Fe0.12Cu0.07Hg0.05Pb0.01)sigma0.98As1.04 based on 7 atoms; the average of 12 analyses of its synthetic analogue is: Pd 73.72, In 16.37, As 9.80, total 99.90 wt.percent, corresponding to Pd5.02In1.03As0.95. The density, calculated on the basis of the empirical formula, is 10.78 g/cm3. The mineral is tetragonal, space group P4/mmm, with a 3.98600(3), c 6.98385(8) angstroem, V 110.961(2) angstroem3, and Z = 1. The crystal structure of synthetic Pd5InAs was solved and refined using powder X-ray-diffraction data from synthetic Pd5InAs. Viteite crystallizes with the Pd5TlAs structure type. The strongest lines in the X-ray powder diffraction pattern of synthetic Pd5InAs [d in angstroem (I) (hkl)] are: 2.3281(45)(003), 2.1932(100)(112), 1.9928(33)(020), 1.2515(17)(115), 1.1857(25)(132). The mineral is named for the Vite river, which flows near the Monchetundra intrusion.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10504 - Mineralogy

Návaznosti výsledku

  • Projekt

    <a href="/cs/project/GA18-15390S" target="_blank" >GA18-15390S: Experimentální a mineralogický výzkum vybraných chalkogenidů a slitin Pt-kovů</a><br>

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Ostatní

  • Rok uplatnění

    2020

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Canadian Mineralogist

  • ISSN

    0008-4476

  • e-ISSN

  • Svazek periodika

    58

  • Číslo periodika v rámci svazku

    3

  • Stát vydavatele periodika

    CA - Kanada

  • Počet stran výsledku

    8

  • Strana od-do

    395-402

  • Kód UT WoS článku

    000549314700007

  • EID výsledku v databázi Scopus

    2-s2.0-85090974653