Drivers of episodic carbonate cementation during the Miocene Climatic Optimum in a paleolake of the Eger Rift

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00025798%3A_____%2F25%3A10169513" target="_blank" >RIV/00025798:_____/25:10169513 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.gca.2025.08.025" target="_blank" >https://doi.org/10.1016/j.gca.2025.08.025</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.gca.2025.08.025" target="_blank" >10.1016/j.gca.2025.08.025</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Drivers of episodic carbonate cementation during the Miocene Climatic Optimum in a paleolake of the Eger Rift

Popis výsledku v původním jazyce

Lacustrine carbonates are sensitive records of climate-driven environmental changes, with carbonates in terrigenous lake successions capturing variations in hydrochemistry, paleoproductivity, and weathering interactions, all potentially influenced by fluctuating atmospheric carbon dioxide levels (pCO&lt;inf&gt;2&lt;/inf&gt;). This complexity underscores the need to explore how various interlinked drivers impact lacustrine carbonate formation and alteration during pivotal climatic periods like the Miocene Climatic Optimum (MCO). Here we investigated ferroan dolomite and siderite as episodic pore-space filling cements within decimeter-scale claystone horizons. The targeted horizons are interbedded with carbonaceous claystone in the Lower Miocene lacustrine succession of the Sokolov sub-basin, Eger Graben, Czech Republic. During the MCO, intensified weathering of shale, K-rich basalt, mafic and granitic bedrocks enriched the paleolake with base cations and soil-derived nutrients. Microbial Fe- and Mn-respiration linked to an active nitrogen cycle sustained elevated shallow burial pore-water alkalinity and pH, driving episodic (Ca, Mg)-Fe carbonate cementation. High dissolved inorganic carbon (DIC), derived from organic matter remineralization and magmatic CO&lt;inf&gt;2&lt;/inf&gt; degassing in the continental rift setting, along with favorable (Mg&lt;sup&gt;2+&lt;/sup&gt; + Fe&lt;sup&gt;2+&lt;/sup&gt;)/Ca&lt;sup&gt;2+&lt;/sup&gt; ratios, facilitated interstitial ferroan dolomite growth in central lake facies, while siderite dominated transitional littoral-to-palustrine environments. The δ&lt;sup&gt;13&lt;/sup&gt;C signatures (median = 8.3 %o, mean = 9.0 %o, range = [+1.8, +18.5]%o) provide evidence for significant methanogenesis influencing dissolved inorganic carbon (DIC) in the pore water-sediment system. Additionally, the lowest δ&lt;sup&gt;13&lt;/sup&gt;C values observed reflect the admixture of &lt;sup&gt;12&lt;/sup&gt;C-enriched DIC derived from magmatic CO&lt;inf&gt;2&lt;/inf&gt; or modified by attendant dissimilatory iron reduction. Bulk δ&lt;sup&gt;15&lt;/sup&gt;N values suggest important nitrogen losses across the paleolake, possibly via denitrification and ammonia volatilization. Based on its clumped isotopologue contents, dolomite cements stabilized in near isotopic equilibrium with diagenetic pore waters at relatively low temperatures, T(Δ&lt;inf&gt;47&lt;/inf&gt;, Δ&lt;inf&gt;48&lt;/inf&gt;) LESS-THAN OR EQUAL TO 58 oC. Rare earth element (REE) patterns and &lt;sup&gt;87&lt;/sup&gt;Sr/&lt;sup&gt;86&lt;/sup&gt;Sr and &lt;sup&gt;143&lt;/sup&gt;Nd/&lt;sup&gt;144&lt;/sup&gt;Nd indicate transport of groundwater evolved after interaction with Paleogene basalts and Paleozoic shale and granitic bedrocks, while Ce anomalies revel a redox-buffered environment favorable to diagenetic carbonate precipitation. These findings highlight complex interactions regulating pore-water carbonate equilibrium in rift lakes. Early Miocene pCO&lt;inf&gt;2&lt;/inf&gt; fluctuations intensified silicate weathering in alkaline igneous rocks of the catchment areas, delivering dolomite-ankerite-siderite reactants (Fe&lt;sup&gt;3+&lt;/sup&gt;, Mg&lt;sup&gt;2+&lt;/sup&gt;, Ca&lt;sup&gt;2+&lt;/sup&gt;) into stagnant paleolakes. Concurrently, soil-derived oxidized nutrients (e.g., phosphate bound to iron oxides) altered the lakes trophic states, driving episodes of elevated productivity that were followed by heightened but stratigraphically localized benthic heterotrophy and element cycling, which had a role in sustained alkalinity generation and pH buffering during cementation.

Název v anglickém jazyce

Drivers of episodic carbonate cementation during the Miocene Climatic Optimum in a paleolake of the Eger Rift

Popis výsledku anglicky

Lacustrine carbonates are sensitive records of climate-driven environmental changes, with carbonates in terrigenous lake successions capturing variations in hydrochemistry, paleoproductivity, and weathering interactions, all potentially influenced by fluctuating atmospheric carbon dioxide levels (pCO&lt;inf&gt;2&lt;/inf&gt;). This complexity underscores the need to explore how various interlinked drivers impact lacustrine carbonate formation and alteration during pivotal climatic periods like the Miocene Climatic Optimum (MCO). Here we investigated ferroan dolomite and siderite as episodic pore-space filling cements within decimeter-scale claystone horizons. The targeted horizons are interbedded with carbonaceous claystone in the Lower Miocene lacustrine succession of the Sokolov sub-basin, Eger Graben, Czech Republic. During the MCO, intensified weathering of shale, K-rich basalt, mafic and granitic bedrocks enriched the paleolake with base cations and soil-derived nutrients. Microbial Fe- and Mn-respiration linked to an active nitrogen cycle sustained elevated shallow burial pore-water alkalinity and pH, driving episodic (Ca, Mg)-Fe carbonate cementation. High dissolved inorganic carbon (DIC), derived from organic matter remineralization and magmatic CO&lt;inf&gt;2&lt;/inf&gt; degassing in the continental rift setting, along with favorable (Mg&lt;sup&gt;2+&lt;/sup&gt; + Fe&lt;sup&gt;2+&lt;/sup&gt;)/Ca&lt;sup&gt;2+&lt;/sup&gt; ratios, facilitated interstitial ferroan dolomite growth in central lake facies, while siderite dominated transitional littoral-to-palustrine environments. The δ&lt;sup&gt;13&lt;/sup&gt;C signatures (median = 8.3 %o, mean = 9.0 %o, range = [+1.8, +18.5]%o) provide evidence for significant methanogenesis influencing dissolved inorganic carbon (DIC) in the pore water-sediment system. Additionally, the lowest δ&lt;sup&gt;13&lt;/sup&gt;C values observed reflect the admixture of &lt;sup&gt;12&lt;/sup&gt;C-enriched DIC derived from magmatic CO&lt;inf&gt;2&lt;/inf&gt; or modified by attendant dissimilatory iron reduction. Bulk δ&lt;sup&gt;15&lt;/sup&gt;N values suggest important nitrogen losses across the paleolake, possibly via denitrification and ammonia volatilization. Based on its clumped isotopologue contents, dolomite cements stabilized in near isotopic equilibrium with diagenetic pore waters at relatively low temperatures, T(Δ&lt;inf&gt;47&lt;/inf&gt;, Δ&lt;inf&gt;48&lt;/inf&gt;) LESS-THAN OR EQUAL TO 58 oC. Rare earth element (REE) patterns and &lt;sup&gt;87&lt;/sup&gt;Sr/&lt;sup&gt;86&lt;/sup&gt;Sr and &lt;sup&gt;143&lt;/sup&gt;Nd/&lt;sup&gt;144&lt;/sup&gt;Nd indicate transport of groundwater evolved after interaction with Paleogene basalts and Paleozoic shale and granitic bedrocks, while Ce anomalies revel a redox-buffered environment favorable to diagenetic carbonate precipitation. These findings highlight complex interactions regulating pore-water carbonate equilibrium in rift lakes. Early Miocene pCO&lt;inf&gt;2&lt;/inf&gt; fluctuations intensified silicate weathering in alkaline igneous rocks of the catchment areas, delivering dolomite-ankerite-siderite reactants (Fe&lt;sup&gt;3+&lt;/sup&gt;, Mg&lt;sup&gt;2+&lt;/sup&gt;, Ca&lt;sup&gt;2+&lt;/sup&gt;) into stagnant paleolakes. Concurrently, soil-derived oxidized nutrients (e.g., phosphate bound to iron oxides) altered the lakes trophic states, driving episodes of elevated productivity that were followed by heightened but stratigraphically localized benthic heterotrophy and element cycling, which had a role in sustained alkalinity generation and pH buffering during cementation.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10505 - Geology

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Geochimica Et Cosmochimica Acta

ISSN

0016-7037

e-ISSN

1872-9533

Svazek periodika

407

Číslo periodika v rámci svazku

15 October 2025

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

20

Strana od-do

47-66

Kód UT WoS článku

001564469900001

EID výsledku v databázi Scopus

2-s2.0-105014544075