Regional geochemical zonation of cultivated floodplains-Application of multi-element associations for soil quality evaluation along the Ohře (Eger) River, Czech Republic

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00027049%3A_____%2F20%3AN0000071" target="_blank" >RIV/00027049:_____/20:N0000071 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00027049:_____/20:N0000072 RIV/00027049:_____/20:N0000070

Výsledek na webu

<a href="https://www-sciencedirect-com.ezproxy.techlib.cz/science/article/pii/S0375674219302092?via%3Dihub" target="_blank" >https://www-sciencedirect-com.ezproxy.techlib.cz/science/article/pii/S0375674219302092?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.gexplo.2020.106491" target="_blank" >10.1016/j.gexplo.2020.106491</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Regional geochemical zonation of cultivated floodplains-Application of multi-element associations for soil quality evaluation along the Ohře (Eger) River, Czech Republic

Popis výsledku v původním jazyce

Floodplains are dynamic ecosystems wherein intensive farming can meet increased environmental concentrations and bioavailability of a number of trace elements. Therefore, the primary objective of this study was to investigate the partial digestion of selected trace elements in surficial soil samples (depth up to 40 cm) across a gradient of environmental conditions along the Wife River and determining the elements of high priority, while also exploring their geographic variation. The established agrochemical testing of Czech soils provides a valuable resource to determine the geochemical differences of multi-element associations in cultivated areas (arable crops and hop fields) in periodically inundated areas in the catchment with a number of potential pollution sources. The topsoil samples were digested using the nitric acid (2 mol/L HNO3), analysed for trace elements (Be, Cd, Co, Cr, Cu, Ni, Pb, V, and Zn) using inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectroscopy (AAS), and for their total Hg content. Data (n = 130) were modelled against the sample location and cultivation using the log-ratio approach. The explanatory and inferential statistical tools (the Mantel s correlation test, PCA, MANOVA) adapted for compositions, combined with a simple spatial ranking and land-use information defined effective discriminating subcomposition (Cu-Hg-Ni) that were able to describe the changes of geochemical domains in floodplains and retained a decent representation (46%) of the entire compositional variability in our dataset. Mapping the Cu-Hg-Ni subcomposition using the RGB composite enabled to display the high-dimensional multivariate dataset with reduced information and enabled to discriminate spatial domains representing geochemical signatures related to changes in element inputs along the watercourse. The analysis of our results within the compositional framework showed a changing pattern of relative enrichment/depletion of the HNO3-extractable trace elements in which a regional contrast between groups of the chalcophile elements (Cu, Pb, Zn, and partly Cd), siderophile transition metals (Cr, Co, Ni, and V) and single elements (Hg, Be) was source-apportioned to the effect of point pollution sources (Hg, Ni, Cr, Co) as well as diffuse sources (Cu, Zn, Pb, Cd).

Název v anglickém jazyce

Regional geochemical zonation of cultivated floodplains-Application of multi-element associations for soil quality evaluation along the Ohře (Eger) River, Czech Republic

Popis výsledku anglicky

Floodplains are dynamic ecosystems wherein intensive farming can meet increased environmental concentrations and bioavailability of a number of trace elements. Therefore, the primary objective of this study was to investigate the partial digestion of selected trace elements in surficial soil samples (depth up to 40 cm) across a gradient of environmental conditions along the Wife River and determining the elements of high priority, while also exploring their geographic variation. The established agrochemical testing of Czech soils provides a valuable resource to determine the geochemical differences of multi-element associations in cultivated areas (arable crops and hop fields) in periodically inundated areas in the catchment with a number of potential pollution sources. The topsoil samples were digested using the nitric acid (2 mol/L HNO3), analysed for trace elements (Be, Cd, Co, Cr, Cu, Ni, Pb, V, and Zn) using inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectroscopy (AAS), and for their total Hg content. Data (n = 130) were modelled against the sample location and cultivation using the log-ratio approach. The explanatory and inferential statistical tools (the Mantel s correlation test, PCA, MANOVA) adapted for compositions, combined with a simple spatial ranking and land-use information defined effective discriminating subcomposition (Cu-Hg-Ni) that were able to describe the changes of geochemical domains in floodplains and retained a decent representation (46%) of the entire compositional variability in our dataset. Mapping the Cu-Hg-Ni subcomposition using the RGB composite enabled to display the high-dimensional multivariate dataset with reduced information and enabled to discriminate spatial domains representing geochemical signatures related to changes in element inputs along the watercourse. The analysis of our results within the compositional framework showed a changing pattern of relative enrichment/depletion of the HNO3-extractable trace elements in which a regional contrast between groups of the chalcophile elements (Cu, Pb, Zn, and partly Cd), siderophile transition metals (Cr, Co, Ni, and V) and single elements (Hg, Be) was source-apportioned to the effect of point pollution sources (Hg, Ni, Cr, Co) as well as diffuse sources (Cu, Zn, Pb, Cd).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

40104 - Soil science

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

JOURNAL OF GEOCHEMICAL EXPLORATION

ISSN

0375-6742

e-ISSN

1879-1689

Svazek periodika

212

Číslo periodika v rámci svazku

May 2020

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

13

Strana od-do

106491

Kód UT WoS článku

000523564700001

EID výsledku v databázi Scopus

2-s2.0-85079555710