From the Decomposition of Chemical Warfare Agents to the Decontamination of Cytostatics

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11110%2F18%3A10376453" target="_blank" >RIV/00216208:11110/18:10376453 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61388980:_____/18:00487621 RIV/29372259:_____/18:N0000031

Výsledek na webu

<a href="https://doi.org/10.1021/acs.iecr.7b04253" target="_blank" >https://doi.org/10.1021/acs.iecr.7b04253</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acs.iecr.7b04253" target="_blank" >10.1021/acs.iecr.7b04253</a>

Jazyk výsledku

angličtina

Název v původním jazyce

From the Decomposition of Chemical Warfare Agents to the Decontamination of Cytostatics

Popis výsledku v původním jazyce

The ability of pilot samples of destructive metal oxide sorbents to decompose a sulfur mustard-type chemical warfare agent into nontoxic products in a nonaqueous solvent was compared with that of the commercial product FAST-ACT. Additionally, samples of the destructive metal oxide sorbents were used to decompose nitrogen mustards, which are used as chemotherapeutic agents, in water, and the results, were compared with those of FAST-ACT. All the prepared pilot samples exhibited stoichiometric activities, i.e., the degradation rate expressed by the rate constant, k [s(-1), min(-1), and the decomposition efficiencies, which are expressed by the degree of conversion d [%], higher than those of the comparative commercial product FAST-ACT. Scaling up the sulfur mustard decomposition from the laboratory conditions (reaction volume, 4 L) to quarter operating (pilot) reaction conditions (reaction volume, 100 L) had a positive effect on the reaction and final product.

Název v anglickém jazyce

From the Decomposition of Chemical Warfare Agents to the Decontamination of Cytostatics

Popis výsledku anglicky

The ability of pilot samples of destructive metal oxide sorbents to decompose a sulfur mustard-type chemical warfare agent into nontoxic products in a nonaqueous solvent was compared with that of the commercial product FAST-ACT. Additionally, samples of the destructive metal oxide sorbents were used to decompose nitrogen mustards, which are used as chemotherapeutic agents, in water, and the results, were compared with those of FAST-ACT. All the prepared pilot samples exhibited stoichiometric activities, i.e., the degradation rate expressed by the rate constant, k [s(-1), min(-1), and the decomposition efficiencies, which are expressed by the degree of conversion d [%], higher than those of the comparative commercial product FAST-ACT. Scaling up the sulfur mustard decomposition from the laboratory conditions (reaction volume, 4 L) to quarter operating (pilot) reaction conditions (reaction volume, 100 L) had a positive effect on the reaction and final product.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

30204 - Oncology

Projekt

—

Návaznosti

V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Industrial and Engineering Chemistry Research

ISSN

0888-5885

e-ISSN

—

Svazek periodika

57

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

9

Strana od-do

2114-2122

Kód UT WoS článku

000425473900035

EID výsledku v databázi Scopus

2-s2.0-85042130591