Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11160%2F16%3A10326171" target="_blank" >RIV/00216208:11160/16:10326171 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.sciencedirect.com/science/article/pii/S0010854515300072" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0010854515300072</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ccr.2015.09.006" target="_blank" >10.1016/j.ccr.2015.09.006</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information

Popis výsledku v původním jazyce

Tetrapyrazinoporphyrazines (TPyzPzs), the heterocyclic azaanalogs of the phthalocyanine macrocycle, are known since 1937 and were intensively studied especially in the last fifteen years. Due to advances in the synthesis, peripherally substituted TPyzPzs and their innumerable metal derivatives have become one of the most easily accessible phthalocyanine analogues. External substituents endow these species with solubility in organic solvents or water, influence aggregation behavior, determine spectral, electrochemical, coordination, acid-base, catalytic and photochemical properties. Moreover, by the building of new exocyclic coordination sites, they enable formation of multimetallic porphyrazines. Aspects concerning the synthesis of precursors, TPyzPz macrocycles and their metal derivatives and the related available structural information are illustrated and discussed in detail in this review including also low symmetry species, oligomeric and polymeric TPyzPzs and higher TPyzPz homologues with fused benzene and heteroaromatic rings.

Název v anglickém jazyce

Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information

Popis výsledku anglicky

Tetrapyrazinoporphyrazines (TPyzPzs), the heterocyclic azaanalogs of the phthalocyanine macrocycle, are known since 1937 and were intensively studied especially in the last fifteen years. Due to advances in the synthesis, peripherally substituted TPyzPzs and their innumerable metal derivatives have become one of the most easily accessible phthalocyanine analogues. External substituents endow these species with solubility in organic solvents or water, influence aggregation behavior, determine spectral, electrochemical, coordination, acid-base, catalytic and photochemical properties. Moreover, by the building of new exocyclic coordination sites, they enable formation of multimetallic porphyrazines. Aspects concerning the synthesis of precursors, TPyzPz macrocycles and their metal derivatives and the related available structural information are illustrated and discussed in detail in this review including also low symmetry species, oligomeric and polymeric TPyzPzs and higher TPyzPz homologues with fused benzene and heteroaromatic rings.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Coordination Chemistry Reviews

ISSN

0010-8545

e-ISSN

—

Svazek periodika

309

Číslo periodika v rámci svazku

February

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

73

Strana od-do

107-179

Kód UT WoS článku

000368956400007

EID výsledku v databázi Scopus

2-s2.0-84949671752