Use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry: A review
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11160%2F19%3A10400652" target="_blank" >RIV/00216208:11160/19:10400652 - isvavai.cz</a>
Výsledek na webu
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=ZEUb7nVGVa" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=ZEUb7nVGVa</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.trac.2019.06.027" target="_blank" >10.1016/j.trac.2019.06.027</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry: A review
Popis výsledku v původním jazyce
The state of the art concerning the use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry thus enabling a variety of applications is reviewed. The preparation of monoliths with thiol groups is achieved via a single-pot strategy or a parent monolith is prepared followed by post-synthesis modification. Both strategies lead to monolithic structures which applications benefit from the reactivity of thiols. Current thiol functionalized monoliths are formed from silica, synthetic polymers, and hybrid organic-silica materials. Preparation of monolithic columns for chromatography is described as well as the production of heterogeneous catalytic reactors in which the affinity of metal nanoparticles to thiols is used. The application of thiol-ene click reactions for the construction of polymer monoliths is then illustrated. Finally, we discuss the hybrid organic-silica monoliths emphasizing their preparation from polyhedral oligomeric silsesquioxanes. These monoliths are well suited for functionalizations and assist the various click reactions.
Název v anglickém jazyce
Use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry: A review
Popis výsledku anglicky
The state of the art concerning the use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry thus enabling a variety of applications is reviewed. The preparation of monoliths with thiol groups is achieved via a single-pot strategy or a parent monolith is prepared followed by post-synthesis modification. Both strategies lead to monolithic structures which applications benefit from the reactivity of thiols. Current thiol functionalized monoliths are formed from silica, synthetic polymers, and hybrid organic-silica materials. Preparation of monolithic columns for chromatography is described as well as the production of heterogeneous catalytic reactors in which the affinity of metal nanoparticles to thiols is used. The application of thiol-ene click reactions for the construction of polymer monoliths is then illustrated. Finally, we discuss the hybrid organic-silica monoliths emphasizing their preparation from polyhedral oligomeric silsesquioxanes. These monoliths are well suited for functionalizations and assist the various click reactions.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10406 - Analytical chemistry
Návaznosti výsledku
Projekt
<a href="/cs/project/EF16_019%2F0000841" target="_blank" >EF16_019/0000841: Zvýšení účinnosti a bezpečnosti léčiv a nutraceutik: moderní metody - nové výzvy</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2019
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Trends in Analytical Chemistry
ISSN
0165-9936
e-ISSN
—
Svazek periodika
118
Číslo periodika v rámci svazku
September
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
19
Strana od-do
606-624
Kód UT WoS článku
000486383900046
EID výsledku v databázi Scopus
2-s2.0-85068582208