Multianalytes Sensing Probe: Fluorescent Moisture Detection, Smartphone Assisted Colorimetric Phosgene recognition and Colorimetric Discrimination of Cu2+ and Fe3+ ions
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11160%2F21%3A10442710" target="_blank" >RIV/00216208:11160/21:10442710 - isvavai.cz</a>
Výsledek na webu
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=giS-1aVnAQ" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=giS-1aVnAQ</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.snb.2020.129026" target="_blank" >10.1016/j.snb.2020.129026</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Multianalytes Sensing Probe: Fluorescent Moisture Detection, Smartphone Assisted Colorimetric Phosgene recognition and Colorimetric Discrimination of Cu2+ and Fe3+ ions
Popis výsledku v původním jazyce
An organic molecule-based sensor 4-((4-(dimethylamino)phenyl)diazenyl)-N-(quinolin-8-yl)benzenesulfonamide (MASP)able to detect multiple analytes such as moisture, warfare reagent (phosgene), divalent (Cu2+), and trivalent (Fe3+) has been reported. These analytes belong to the different classes of chemicals and barely interfere in the real sample. Fluorescence emission of MASP was observed due to the ESIPT mechanism, but it was inhibited by water. This phenomenon was utilized for moisture detection in DMSO and THF with the detection limit of 0.0032 % w/w and 0.0014 % w/w, respectively. The MASP was also employed for the colorimetric sensing (yellow to red) of phosgene in solution and gas with good selectivity and high sensitivity (LOD = 23 nM). The naked eye detection of MASP was incorporated with RGB color value to make use of MASP for the practical application using a smartphone as a portable analytical device. The distinct color change of divalent Cu2+ (yellow to colorless) and trivalent Fe3+ (yellow to red) observed with MASP also helps discriminate Cu2+ and Fe3+ among various cations.
Název v anglickém jazyce
Multianalytes Sensing Probe: Fluorescent Moisture Detection, Smartphone Assisted Colorimetric Phosgene recognition and Colorimetric Discrimination of Cu2+ and Fe3+ ions
Popis výsledku anglicky
An organic molecule-based sensor 4-((4-(dimethylamino)phenyl)diazenyl)-N-(quinolin-8-yl)benzenesulfonamide (MASP)able to detect multiple analytes such as moisture, warfare reagent (phosgene), divalent (Cu2+), and trivalent (Fe3+) has been reported. These analytes belong to the different classes of chemicals and barely interfere in the real sample. Fluorescence emission of MASP was observed due to the ESIPT mechanism, but it was inhibited by water. This phenomenon was utilized for moisture detection in DMSO and THF with the detection limit of 0.0032 % w/w and 0.0014 % w/w, respectively. The MASP was also employed for the colorimetric sensing (yellow to red) of phosgene in solution and gas with good selectivity and high sensitivity (LOD = 23 nM). The naked eye detection of MASP was incorporated with RGB color value to make use of MASP for the practical application using a smartphone as a portable analytical device. The distinct color change of divalent Cu2+ (yellow to colorless) and trivalent Fe3+ (yellow to red) observed with MASP also helps discriminate Cu2+ and Fe3+ among various cations.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
30104 - Pharmacology and pharmacy
Návaznosti výsledku
Projekt
<a href="/cs/project/EF16_019%2F0000841" target="_blank" >EF16_019/0000841: Zvýšení účinnosti a bezpečnosti léčiv a nutraceutik: moderní metody - nové výzvy</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2021
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Sensors and Actuators B: Chemical
ISSN
0925-4005
e-ISSN
—
Svazek periodika
328
Číslo periodika v rámci svazku
February
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
10
Strana od-do
129026
Kód UT WoS článku
000600963400006
EID výsledku v databázi Scopus
2-s2.0-85092931506