Crossed-Beam Scattering Studies of Electron-Transfer Processes between the Dication CO22+ and Neutral CO2: Electronic States of Reactants and Products Involved

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10062541" target="_blank" >RIV/00216208:11310/10:10062541 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61388955:_____/10:00345108 RIV/61388963:_____/10:00345108

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Crossed-Beam Scattering Studies of Electron-Transfer Processes between the Dication CO22+ and Neutral CO2: Electronic States of Reactants and Products Involved

Popis výsledku v původním jazyce

Crossed-beam scattering experiments were carried out at collision energies of 4.51 and 2.71 eV to elucidate the electronic states involved in the nondissociative and dissociative electron-transfer reactions observed following CO22+/CO2 collisions. Specifically, we focus on the observation that, in the dissociative electron-transfer reaction, forming CO+, the majority of the CO+ product ions are formed via electron capture by the CO22+ rather than via ejection of an electron from the neutral CO2 reactionpartner. The main channels resulting in nondissociative electron transfer are reactions of the ground (X-3 Sigma(-)(g)) and excited states of CO22+ to give different combinations of the ground and excited states of the product pair of CO2+ ions in whichthe combination AA appears to be significant.

Název v anglickém jazyce

Crossed-Beam Scattering Studies of Electron-Transfer Processes between the Dication CO22+ and Neutral CO2: Electronic States of Reactants and Products Involved

Popis výsledku anglicky

Crossed-beam scattering experiments were carried out at collision energies of 4.51 and 2.71 eV to elucidate the electronic states involved in the nondissociative and dissociative electron-transfer reactions observed following CO22+/CO2 collisions. Specifically, we focus on the observation that, in the dissociative electron-transfer reaction, forming CO+, the majority of the CO+ product ions are formed via electron capture by the CO22+ rather than via ejection of an electron from the neutral CO2 reactionpartner. The main channels resulting in nondissociative electron transfer are reactions of the ground (X-3 Sigma(-)(g)) and excited states of CO22+ to give different combinations of the ground and excited states of the product pair of CO2+ ions in whichthe combination AA appears to be significant.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of physical chemistry a

ISSN

1089-5639

e-ISSN

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Svazek periodika

114

Číslo periodika v rámci svazku

23

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

9

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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