Ionic liquid-induced formation of polyaniline nanostructures during the chemical polymerization of aniline in an acidic aqueous medium
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10062583" target="_blank" >RIV/00216208:11310/10:10062583 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Ionic liquid-induced formation of polyaniline nanostructures during the chemical polymerization of aniline in an acidic aqueous medium
Popis výsledku v původním jazyce
Nanostructured polyanilines (PANIs) with a variety of morphologies were synthesized in acidic aqueous solutions with an added ionic liquid, 1-butyl-3-methylimidazolium chloride. The influence of various reaction conditions, i.e., the molar ratio of aniline to ionic liquid and initial aniline concentration, on the morphology and properties of the synthesized PANIs were investigated. The morphologies of the PANIs, as studied by scanning electron microscopy (SEM), range from nanowires to complex three-dimensional structures and were influenced particularly by the molar ratio of aniline to ionic liquid. The chemical structure and molecular-weight characteristics, as determined by Fourier-transform infrared spectroscopy (FTIR), UV-Vis spectroscopy and size-exclusion chromatography (SEC), were not affected by the reaction conditions, indicating that the aniline polymerization mechanism did not change in the presence of the ionic liquid, which acted as a soft template.
Název v anglickém jazyce
Ionic liquid-induced formation of polyaniline nanostructures during the chemical polymerization of aniline in an acidic aqueous medium
Popis výsledku anglicky
Nanostructured polyanilines (PANIs) with a variety of morphologies were synthesized in acidic aqueous solutions with an added ionic liquid, 1-butyl-3-methylimidazolium chloride. The influence of various reaction conditions, i.e., the molar ratio of aniline to ionic liquid and initial aniline concentration, on the morphology and properties of the synthesized PANIs were investigated. The morphologies of the PANIs, as studied by scanning electron microscopy (SEM), range from nanowires to complex three-dimensional structures and were influenced particularly by the molar ratio of aniline to ionic liquid. The chemical structure and molecular-weight characteristics, as determined by Fourier-transform infrared spectroscopy (FTIR), UV-Vis spectroscopy and size-exclusion chromatography (SEC), were not affected by the reaction conditions, indicating that the aniline polymerization mechanism did not change in the presence of the ionic liquid, which acted as a soft template.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CD - Makromolekulární chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
<a href="/cs/project/KAN100500652" target="_blank" >KAN100500652: Heterogenní organické a hybridní nanokompozitní materiály pro solární články</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Ostatní
Rok uplatnění
2010
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Synthetic Metals
ISSN
0379-6779
e-ISSN
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Svazek periodika
160
Číslo periodika v rámci svazku
15-16
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
6
Strana od-do
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Kód UT WoS článku
000281361300031
EID výsledku v databázi Scopus
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