Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10081686" target="_blank" >RIV/00216208:11310/10:10081686 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O

Popis výsledku v původním jazyce

The decavanadate with a novel glycine-glycinato complex of copper (II) in the cationic part, (NH4)(2)(Cu-2 (H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28 center dot 6H(2)O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O- and monodentate O- coordination of glycine to the same central atom was observed for the first time.

Název v anglickém jazyce

Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O

Popis výsledku anglicky

The decavanadate with a novel glycine-glycinato complex of copper (II) in the cationic part, (NH4)(2)(Cu-2 (H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28 center dot 6H(2)O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O- and monodentate O- coordination of glycine to the same central atom was observed for the first time.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganic Chemistry Communication

ISSN

1387-7003

e-ISSN

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Svazek periodika

13

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

3

Strana od-do

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Kód UT WoS článku

000282867800012

EID výsledku v databázi Scopus

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