Synthesis, molecular structure and electrochemistry of gold(I) complexes with 1-(diphenylphosphino)-1'-[(diphenylphosphino)methyl]ferrocene

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10126173" target="_blank" >RIV/00216208:11310/12:10126173 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.jorganchem.2012.06.007" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2012.06.007</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2012.06.007" target="_blank" >10.1016/j.jorganchem.2012.06.007</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, molecular structure and electrochemistry of gold(I) complexes with 1-(diphenylphosphino)-1'-[(diphenylphosphino)methyl]ferrocene

Popis výsledku v původním jazyce

Depending on the reaction stoichiometry, 1-(diphenylphosphino)-1'-[(diphenylphosphino) methyl]ferrocene (1) reacts with [AuCl(tht)] (tht = tetrahydrothiophene) to afford an insoluble polymer formulated as [AuCl(1)]n (2) or ligand-bridged digold(I) complex, [(mu-1)(AuCl)2] (3). The latter compound readily undergoes metathesis reactions with anionic reagents such as in situ generated acetylides, thiocyanate or N,N-diethyldithiocarbamate to give the corresponding digold(I) complexes [(mu-1)(AuY)2], where Yis CCPh (4), CCFc (5; Fc = ferrocenyl), SCN (6), and Et2NCS2 (7). Similar reaction of 3 with a dithiolate formed from propane-1,3-dithiol and sodium methoxide affords a macrocyclic bis-chelate [(mu-1)(AuSCH2CH2CH2SAu)] (8). Compounds 2-8 have been characterized by spectroscopic methods (multinuclear NMR, ESI, MS, UV-vis and IR) and by elemental analysis, and the molecular structures of 3.1/2C2H4Cl2, 4.2CHCl3, 7.2CHCl3, and 8 have been determined by single-crystal X-ray diffraction analy

Název v anglickém jazyce

Synthesis, molecular structure and electrochemistry of gold(I) complexes with 1-(diphenylphosphino)-1'-[(diphenylphosphino)methyl]ferrocene

Popis výsledku anglicky

Depending on the reaction stoichiometry, 1-(diphenylphosphino)-1'-[(diphenylphosphino) methyl]ferrocene (1) reacts with [AuCl(tht)] (tht = tetrahydrothiophene) to afford an insoluble polymer formulated as [AuCl(1)]n (2) or ligand-bridged digold(I) complex, [(mu-1)(AuCl)2] (3). The latter compound readily undergoes metathesis reactions with anionic reagents such as in situ generated acetylides, thiocyanate or N,N-diethyldithiocarbamate to give the corresponding digold(I) complexes [(mu-1)(AuY)2], where Yis CCPh (4), CCFc (5; Fc = ferrocenyl), SCN (6), and Et2NCS2 (7). Similar reaction of 3 with a dithiolate formed from propane-1,3-dithiol and sodium methoxide affords a macrocyclic bis-chelate [(mu-1)(AuSCH2CH2CH2SAu)] (8). Compounds 2-8 have been characterized by spectroscopic methods (multinuclear NMR, ESI, MS, UV-vis and IR) and by elemental analysis, and the molecular structures of 3.1/2C2H4Cl2, 4.2CHCl3, 7.2CHCl3, and 8 have been determined by single-crystal X-ray diffraction analy

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP207%2F10%2F0176" target="_blank" >GAP207/10/0176: Homologické funkční fosfinoferrocenové ligandy pro koordinační chemii a katalýzu</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

—

Svazek periodika

716

Číslo periodika v rámci svazku

neuveden

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

10

Strana od-do

110-119

Kód UT WoS článku

000307821700016

EID výsledku v databázi Scopus

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