Crystallization and characterization of the compounds Gly.MSO4.mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m = 0, 3, 5, 6)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10127269" target="_blank" >RIV/00216208:11310/12:10127269 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61388980:_____/12:00377358

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molstruc.2012.02.068" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2012.02.068</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2012.02.068" target="_blank" >10.1016/j.molstruc.2012.02.068</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Crystallization and characterization of the compounds Gly.MSO4.mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m = 0, 3, 5, 6)

Popis výsledku v původním jazyce

The equilibrium crystallization of complex compounds of the type Gly.MSO4.5H2O with a structure derived from those of the crystallized double salts MSO4.xH2O, where x = 6, 7 was predicted and proven in the systems Gly-MSO4-H2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+ and Zn2+). It was predicted that stable octahedral complexes [M(H2O)6]2+ and trans-[M(H2O)4(O-gly)2]2+, as well as [SO4]2MINUS SIGN tetrahedra, which were the main building units of the crystallizing Gly.MSO4.5H2O compounds (triclinic crystal system, space group P MINUS SIGN 1), were predominating in these solutions. The vibrational spectra and the thermal behavior of the Gly.MSO4.5H2O compounds (M = Mg2+, Co2+, Zn2+) are in accord with the refined crystal structures. The cobalt compound displaysantiferromagnetic behavior whereas the nickel and manganese compounds are ferromagnetic. In the manganese system where MnSO4.H2O (308 K) crystallizes, the only complex compound is the anhydrous Gly.MnSO4 with a polymeric type structure .

Název v anglickém jazyce

Crystallization and characterization of the compounds Gly.MSO4.mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m = 0, 3, 5, 6)

Popis výsledku anglicky

The equilibrium crystallization of complex compounds of the type Gly.MSO4.5H2O with a structure derived from those of the crystallized double salts MSO4.xH2O, where x = 6, 7 was predicted and proven in the systems Gly-MSO4-H2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+ and Zn2+). It was predicted that stable octahedral complexes [M(H2O)6]2+ and trans-[M(H2O)4(O-gly)2]2+, as well as [SO4]2MINUS SIGN tetrahedra, which were the main building units of the crystallizing Gly.MSO4.5H2O compounds (triclinic crystal system, space group P MINUS SIGN 1), were predominating in these solutions. The vibrational spectra and the thermal behavior of the Gly.MSO4.5H2O compounds (M = Mg2+, Co2+, Zn2+) are in accord with the refined crystal structures. The cobalt compound displaysantiferromagnetic behavior whereas the nickel and manganese compounds are ferromagnetic. In the manganese system where MnSO4.H2O (308 K) crystallizes, the only complex compound is the anhydrous Gly.MnSO4 with a polymeric type structure .

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA203%2F09%2F0878" target="_blank" >GA203/09/0878: Krystalové inženýrství materiálů s vodíkovými vazbami pro nelineární optiku</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

1018

Číslo periodika v rámci svazku

březen

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

113-121

Kód UT WoS článku

000305847100019

EID výsledku v databázi Scopus

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