Selective borane reduction of phosphinoferrocene carbaldehydes to phosphinoalcohol-borane adducts. The coordination behaviour of 1-(diphenylphosphino)-1 '-(methoxymethyl)ferrocene, a new ferrocene O,P-hybrid donor prepared from such an adduct

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10133859" target="_blank" >RIV/00216208:11310/13:10133859 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1039/c2dt32511j" target="_blank" >http://dx.doi.org/10.1039/c2dt32511j</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c2dt32511j" target="_blank" >10.1039/c2dt32511j</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Selective borane reduction of phosphinoferrocene carbaldehydes to phosphinoalcohol-borane adducts. The coordination behaviour of 1-(diphenylphosphino)-1 '-(methoxymethyl)ferrocene, a new ferrocene O,P-hybrid donor prepared from such an adduct

Popis výsledku v původním jazyce

The reduction of ferrocene phosphino-aldehydes, R2PfcCHO (R = Ph, 2; Cy, 3; fc = ferrocene-1,1'-diyl, Cy = cyclohexyl) and (S-p)-[Fe(eta(5)-C5H3-1-CHO-2-PPh2)(eta(5)-C5H5)] ((Sp)-4), with BH3*THF or BH3*SMe2 in THF at 0 degrees C selectively afforded thecorresponding phosphinoalcohol-borane adducts, R2PfcCH2OH*BH3 (R = Ph, 5; Cy, 6) and (Sp)-[Fe(eta(5)-C5H3-1-CH2OH-2-PPh2)(eta(5)-C5H5)]*BH3 ((Sp)-7), in quantitative yields. In contrast, the reactions performed at elevated temperatures favoured the formation of methyl derivatives (e. g., Ph2PfcCH3*BH3 (8)) resulting from overreduction (deoxygenation). The crystal structures of 3, 5, (Sp)-7, 8 and Cy2PfcBr (9) have been determined by single-crystal X-ray diffraction analysis. The crystal assemblies of adducts 5 and (Sp)-7 are built up by means of C-H...O contacts, O-H...HB dihydrogen bonds and other soft interactions but, surprisingly, not via the conventional O-H...O hydrogen bonds. Adduct 5 was smoothly deprotected to give the corresp

Název v anglickém jazyce

Selective borane reduction of phosphinoferrocene carbaldehydes to phosphinoalcohol-borane adducts. The coordination behaviour of 1-(diphenylphosphino)-1 '-(methoxymethyl)ferrocene, a new ferrocene O,P-hybrid donor prepared from such an adduct

Popis výsledku anglicky

The reduction of ferrocene phosphino-aldehydes, R2PfcCHO (R = Ph, 2; Cy, 3; fc = ferrocene-1,1'-diyl, Cy = cyclohexyl) and (S-p)-[Fe(eta(5)-C5H3-1-CHO-2-PPh2)(eta(5)-C5H5)] ((Sp)-4), with BH3*THF or BH3*SMe2 in THF at 0 degrees C selectively afforded thecorresponding phosphinoalcohol-borane adducts, R2PfcCH2OH*BH3 (R = Ph, 5; Cy, 6) and (Sp)-[Fe(eta(5)-C5H3-1-CH2OH-2-PPh2)(eta(5)-C5H5)]*BH3 ((Sp)-7), in quantitative yields. In contrast, the reactions performed at elevated temperatures favoured the formation of methyl derivatives (e. g., Ph2PfcCH3*BH3 (8)) resulting from overreduction (deoxygenation). The crystal structures of 3, 5, (Sp)-7, 8 and Cy2PfcBr (9) have been determined by single-crystal X-ray diffraction analysis. The crystal assemblies of adducts 5 and (Sp)-7 are built up by means of C-H...O contacts, O-H...HB dihydrogen bonds and other soft interactions but, surprisingly, not via the conventional O-H...O hydrogen bonds. Adduct 5 was smoothly deprotected to give the corresp

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP207%2F10%2F0176" target="_blank" >GAP207/10/0176: Homologické funkční fosfinoferrocenové ligandy pro koordinační chemii a katalýzu</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Svazek periodika

42

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

17

Strana od-do

3373-3389

Kód UT WoS článku

000314783300014

EID výsledku v databázi Scopus

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