A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10139219" target="_blank" >RIV/00216208:11310/13:10139219 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/61388955:_____/13:00395582
Výsledek na webu
<a href="http://dx.doi.org/10.1002/aoc.2987" target="_blank" >http://dx.doi.org/10.1002/aoc.2987</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/aoc.2987" target="_blank" >10.1002/aoc.2987</a>

Jazyk výsledku
angličtina
Název v původním jazyce
A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface
Popis výsledku v původním jazyce
Mesoporous molecular sieve SBA-15 and conventional silica gel were grafted with 3-[2-(diethylamino)ethylamino]propyl groups and used as supports for the preparation of deposited palladium catalysts, which were subsequently evaluated in Stille cross-coupling reaction of aryl bromides. The highest conversions were achieved with the metal-saturated catalyst resulting from the modified SBA-15. Influence of various reaction parameters (solvent, additive, temperature, etc.) on the overall yield and selectivity was studied.
Název v anglickém jazyce
A study into Stille cross-coupling reaction mediated by palladium catalysts deposited over siliceous supports bearing N-donor groups at the surface
Popis výsledku anglicky
Mesoporous molecular sieve SBA-15 and conventional silica gel were grafted with 3-[2-(diethylamino)ethylamino]propyl groups and used as supports for the preparation of deposited palladium catalysts, which were subsequently evaluated in Stille cross-coupling reaction of aryl bromides. The highest conversions were achieved with the metal-saturated catalyst resulting from the modified SBA-15. Influence of various reaction parameters (solvent, additive, temperature, etc.) on the overall yield and selectivity was studied.

Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CF - Fyzikální chemie a teoretická chemie
OECD FORD obor
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Projekt
<a href="/cs/project/GA104%2F09%2F0561" target="_blank" >GA104/09/0561: Deponované nanočásticové katalyzátory pro tvorbu vazeb C-C</a><br>
Návaznosti
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění
2013
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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