Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10292899" target="_blank" >RIV/00216208:11310/15:10292899 - isvavai.cz</a>

Výsledek na webu

<a href="http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03279a" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03279a</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c4dt03279a" target="_blank" >10.1039/c4dt03279a</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands

Popis výsledku v původním jazyce

The reaction of in situ generated 1'-(diphenylphosphino)-1-lithioferrocene with carbamoyl chlorides, ClC-(E) NMe2, affords the corresponding (thio) amides, Ph(2)PfcC(E) NMe2 (E = O (2), S (3); fc = ferrocene-1,1'-diyl). These compounds as well as their analogues, Ph(2)PfcC(O) NHMe (4) and Ph(2)PfcC(O) NH2 (5), prepared from 1'-(diphenylphosphino) ferrocene-1-carboxylic acid (Hdpf) were studied as ligands for the Group 11 metal ions. In the reactions with [Cu(MeCN)(4)][BF4], the amides give rise to bis-chelate complexes of the type [Cu(L-kappa O-2, P)(2)][BF4]. Similar products, [Ag(L-kappa O-2, P)(2)] ClO4, are obtained from silver(I) perchlorate and 2, 4 or 5. In contrast, the reaction of AgClO4 with 3 produces a unique molecular dimer [Ag(3)-(ClO4-kappa O)](2), where the metal centres are bridged by the sulfur atoms of the P, S-chelating thioamides. The reactions of 2-5 with [AuCl(tht)] (tht = tetrahydrothiophene) afford the expected gold(I)-phosphine complexes, [AuCl(L-kappa P)], co

Název v anglickém jazyce

Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands

Popis výsledku anglicky

The reaction of in situ generated 1'-(diphenylphosphino)-1-lithioferrocene with carbamoyl chlorides, ClC-(E) NMe2, affords the corresponding (thio) amides, Ph(2)PfcC(E) NMe2 (E = O (2), S (3); fc = ferrocene-1,1'-diyl). These compounds as well as their analogues, Ph(2)PfcC(O) NHMe (4) and Ph(2)PfcC(O) NH2 (5), prepared from 1'-(diphenylphosphino) ferrocene-1-carboxylic acid (Hdpf) were studied as ligands for the Group 11 metal ions. In the reactions with [Cu(MeCN)(4)][BF4], the amides give rise to bis-chelate complexes of the type [Cu(L-kappa O-2, P)(2)][BF4]. Similar products, [Ag(L-kappa O-2, P)(2)] ClO4, are obtained from silver(I) perchlorate and 2, 4 or 5. In contrast, the reaction of AgClO4 with 3 produces a unique molecular dimer [Ag(3)-(ClO4-kappa O)](2), where the metal centres are bridged by the sulfur atoms of the P, S-chelating thioamides. The reactions of 2-5 with [AuCl(tht)] (tht = tetrahydrothiophene) afford the expected gold(I)-phosphine complexes, [AuCl(L-kappa P)], co

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA13-08890S" target="_blank" >GA13-08890S: Polární ferrocenové amidofosfinové ligandy pro katalytické aplikace</a><br>

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Dalton Transactions

ISSN

1477-9226

e-ISSN

—

Svazek periodika

44

Číslo periodika v rámci svazku

7

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

17

Strana od-do

3092-3108

Kód UT WoS článku

000349403100022

EID výsledku v databázi Scopus

2-s2.0-84922655863