Determination of As by UV-photochemical generation of its volatile species with AAS detection

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F16%3A10325547" target="_blank" >RIV/00216208:11310/16:10325547 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1007/s00706-016-1808-5" target="_blank" >http://dx.doi.org/10.1007/s00706-016-1808-5</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s00706-016-1808-5" target="_blank" >10.1007/s00706-016-1808-5</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Determination of As by UV-photochemical generation of its volatile species with AAS detection

Popis výsledku v původním jazyce

This work was focused on the development of an analytical method for determination of arsenic in liquid (aqueous solutions of arsenite) by UV-photochemical generation of its volatile compounds. The study contains the optimization, method characterisation and also a study of the influence of selected compounds on the signal measured. The method involves a combination of flow injection analysis, UV-photochemical generation of volatile compounds of arsenic in flow injection arrangement and atomic absorption spectrometry using an externally heated quartz tube atomizer. The attained absorbance was very low after the optimization. In the next step, the influence of selected compounds on UV-photochemical generation was investigated with the aim to find a suitable reaction modifier that would improve the sensitivity of arsenic determination. Bi(III) was found as the best reaction modifier not only for causing the increase of the signal of arsenic measured but also for its persisting effect. The activation with concentration of 10 mg dm(-3) of Bi(III) increases the absorbance of arsenic approximately eleven times compared to signals without activation. Following method characteristics were achieved under the optimum experimental conditions: the limit of detection of 18 A mu g dm(-3), the repeatability of 4.5 % expressed as % RSD at 200 A mu g dm(-3), and linear dynamic range 60-500 A mu g dm(-3) of arsenic.

Název v anglickém jazyce

Determination of As by UV-photochemical generation of its volatile species with AAS detection

Popis výsledku anglicky

This work was focused on the development of an analytical method for determination of arsenic in liquid (aqueous solutions of arsenite) by UV-photochemical generation of its volatile compounds. The study contains the optimization, method characterisation and also a study of the influence of selected compounds on the signal measured. The method involves a combination of flow injection analysis, UV-photochemical generation of volatile compounds of arsenic in flow injection arrangement and atomic absorption spectrometry using an externally heated quartz tube atomizer. The attained absorbance was very low after the optimization. In the next step, the influence of selected compounds on UV-photochemical generation was investigated with the aim to find a suitable reaction modifier that would improve the sensitivity of arsenic determination. Bi(III) was found as the best reaction modifier not only for causing the increase of the signal of arsenic measured but also for its persisting effect. The activation with concentration of 10 mg dm(-3) of Bi(III) increases the absorbance of arsenic approximately eleven times compared to signals without activation. Following method characteristics were achieved under the optimum experimental conditions: the limit of detection of 18 A mu g dm(-3), the repeatability of 4.5 % expressed as % RSD at 200 A mu g dm(-3), and linear dynamic range 60-500 A mu g dm(-3) of arsenic.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CB - Analytická chemie, separace

OECD FORD obor

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Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Monatshefte für Chemie

ISSN

0026-9247

e-ISSN

—

Svazek periodika

147

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

AT - Rakouská republika

Počet stran výsledku

8

Strana od-do

1447-1454

Kód UT WoS článku

000380695200017

EID výsledku v databázi Scopus

2-s2.0-84979680782