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Transformation of arsenic-rich copper smelter flue dust in contrasting soils: A 2-year field experiment

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10375227" target="_blank" >RIV/00216208:11310/18:10375227 - isvavai.cz</a>

  • Nalezeny alternativní kódy

    RIV/68081715:_____/18:00487092 RIV/60460709:41210/18:76896

  • Výsledek na webu

    <a href="https://doi.org/10.1016/j.envpol.2018.02.028" target="_blank" >https://doi.org/10.1016/j.envpol.2018.02.028</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.envpol.2018.02.028" target="_blank" >10.1016/j.envpol.2018.02.028</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Transformation of arsenic-rich copper smelter flue dust in contrasting soils: A 2-year field experiment

  • Popis výsledku v původním jazyce

    Dust emissions from copper smelters processing arsenic-bearing ores represent a risk to soil environments due to the high levels of As and other inorganic contaminants. Using an in situ experiment in four different forest and grassland soils (pH 3.2-8.0) we studied the transformation of As-rich (&gt;50 wt% As) copper smelter dust over 24 months. Double polyamide bags with 1 g of flue dust were buried at different depths in soil pits and in 6-month intervals; then those bags, surrounding soil columns, and soil pore waters were collected and analysed. Dust dissolution was relatively fast during the first 6 months (5-34%), and mass losses attained 52% after 24 months. The key driving forces affecting dust dissolution were not only pH, but also the water percolation retention in individual soils. Primary arsenolite (As2O3) dissolution was responsible for high As release from the dust (to 72%) and substantial increase of As in the soil (to a 56 x increase; to 1500 mg kg(-1)). Despite high arsenolite solubility, this phase persisted in the dust after 2 years of exposure. Mineralogical investigation indicated that mimetite [Pb-5(AsO4)(3)(Cl,OH)], unidentified complex Ca-Pb-Fe-Zn arsenates, and Fe oxyhydroxides partly controlled the mobility of As and other metal(loid)s. Compared to As, other less abundant contaminants (Bi, Cu, Pb, Sb, Zn) were released into the soil to a lesser extent (8-40% of total). The relatively high mobility of As in the soil can be seen from decreases of bulk As concentrations after spring snowmelt, high water-extractable fractions with up to similar to 50% of As(III) in extracts, and high As concentrations in soil pore waters. Results indicate that efficient controls of emissions from copper smelters and flue dust disposal sites are needed to prevent extensive contamination of nearby soils by persistent As.

  • Název v anglickém jazyce

    Transformation of arsenic-rich copper smelter flue dust in contrasting soils: A 2-year field experiment

  • Popis výsledku anglicky

    Dust emissions from copper smelters processing arsenic-bearing ores represent a risk to soil environments due to the high levels of As and other inorganic contaminants. Using an in situ experiment in four different forest and grassland soils (pH 3.2-8.0) we studied the transformation of As-rich (&gt;50 wt% As) copper smelter dust over 24 months. Double polyamide bags with 1 g of flue dust were buried at different depths in soil pits and in 6-month intervals; then those bags, surrounding soil columns, and soil pore waters were collected and analysed. Dust dissolution was relatively fast during the first 6 months (5-34%), and mass losses attained 52% after 24 months. The key driving forces affecting dust dissolution were not only pH, but also the water percolation retention in individual soils. Primary arsenolite (As2O3) dissolution was responsible for high As release from the dust (to 72%) and substantial increase of As in the soil (to a 56 x increase; to 1500 mg kg(-1)). Despite high arsenolite solubility, this phase persisted in the dust after 2 years of exposure. Mineralogical investigation indicated that mimetite [Pb-5(AsO4)(3)(Cl,OH)], unidentified complex Ca-Pb-Fe-Zn arsenates, and Fe oxyhydroxides partly controlled the mobility of As and other metal(loid)s. Compared to As, other less abundant contaminants (Bi, Cu, Pb, Sb, Zn) were released into the soil to a lesser extent (8-40% of total). The relatively high mobility of As in the soil can be seen from decreases of bulk As concentrations after spring snowmelt, high water-extractable fractions with up to similar to 50% of As(III) in extracts, and high As concentrations in soil pore waters. Results indicate that efficient controls of emissions from copper smelters and flue dust disposal sites are needed to prevent extensive contamination of nearby soils by persistent As.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10505 - Geology

Návaznosti výsledku

  • Projekt

    <a href="/cs/project/GA13-17501S" target="_blank" >GA13-17501S: Reaktivita antropogenních geomateriálů s obsahem kovů v půdách</a><br>

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Ostatní

  • Rok uplatnění

    2018

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Environmental Pollution

  • ISSN

    0269-7491

  • e-ISSN

  • Svazek periodika

    237

  • Číslo periodika v rámci svazku

    JUNE

  • Stát vydavatele periodika

    GB - Spojené království Velké Británie a Severního Irska

  • Počet stran výsledku

    10

  • Strana od-do

    83-92

  • Kód UT WoS článku

    000431158900009

  • EID výsledku v databázi Scopus

    2-s2.0-85042388769