Synthesis and Structural Characterisation of an N-Phosphanyl Ferrocene Carboxamide and its Ruthenium, Rhodium and Palladium Complexes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10413840" target="_blank" >RIV/00216208:11310/20:10413840 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=CP6mSOffnp" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=CP6mSOffnp</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/cplu.202000303" target="_blank" >10.1002/cplu.202000303</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis and Structural Characterisation of an N-Phosphanyl Ferrocene Carboxamide and its Ruthenium, Rhodium and Palladium Complexes

Popis výsledku v původním jazyce

[((Diphenylphosphanyl)amino)carbonyl]ferrocene (1) has been synthesized and coordinated to light platinum metals, ruthenium, rhodium and palladium, in diverse coordination modes. Specifically, compound1was used to prepare the following phosphane complexes, [(η(6)-mes)RuCl2(1-κP)], [(η(5)-C5Me5)RhCl2(1-κP)],trans-[PdCl2(1-κP)(2)], and [(L-NC)PdCl(1-κP)] (mes=mesitylene, L-NC=[2-(dimethylamino-κ N)methyl]phenyl-κC-1). They were subsequently converted into cationic O,P-chelate complexes by halide abstraction with AgClO(4)and into neutral O,P-chelate complexes by deprotonation with potassiumtert-butoxide. All coordination compounds and phosphane chalcogenides1E(P-bound chalcogen atom E=O, S and Se), which were also synthesised, were structurally characterised using spectroscopic methods (IR, multinuclear NMR and ESI MS) and single-crystal X-ray diffraction analysis. The electrochemical behaviour of the prepared compounds was studied by cyclic voltammetry, and the (L-NC)Pd-1complexes were further studied by Mossbauer spectroscopy.

Název v anglickém jazyce

Synthesis and Structural Characterisation of an N-Phosphanyl Ferrocene Carboxamide and its Ruthenium, Rhodium and Palladium Complexes

Popis výsledku anglicky

[((Diphenylphosphanyl)amino)carbonyl]ferrocene (1) has been synthesized and coordinated to light platinum metals, ruthenium, rhodium and palladium, in diverse coordination modes. Specifically, compound1was used to prepare the following phosphane complexes, [(η(6)-mes)RuCl2(1-κP)], [(η(5)-C5Me5)RhCl2(1-κP)],trans-[PdCl2(1-κP)(2)], and [(L-NC)PdCl(1-κP)] (mes=mesitylene, L-NC=[2-(dimethylamino-κ N)methyl]phenyl-κC-1). They were subsequently converted into cationic O,P-chelate complexes by halide abstraction with AgClO(4)and into neutral O,P-chelate complexes by deprotonation with potassiumtert-butoxide. All coordination compounds and phosphane chalcogenides1E(P-bound chalcogen atom E=O, S and Se), which were also synthesised, were structurally characterised using spectroscopic methods (IR, multinuclear NMR and ESI MS) and single-crystal X-ray diffraction analysis. The electrochemical behaviour of the prepared compounds was studied by cyclic voltammetry, and the (L-NC)Pd-1complexes were further studied by Mossbauer spectroscopy.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA19-09334S" target="_blank" >GA19-09334S: Nekonvenční ferrocenové fosfiny</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ChemPlusChem

ISSN

2192-6506

e-ISSN

—

Svazek periodika

85

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

14

Strana od-do

1325-1338

Kód UT WoS článku

000544057700027

EID výsledku v databázi Scopus

2-s2.0-85086852568