Intermolecular interactions in the crystal structures of chlorogold(I) complexes with N-phosphinoamide ligands

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F21%3A10427843" target="_blank" >RIV/00216208:11310/21:10427843 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=hfeLLD9QrI" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=hfeLLD9QrI</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ica.2020.120138" target="_blank" >10.1016/j.ica.2020.120138</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Intermolecular interactions in the crystal structures of chlorogold(I) complexes with N-phosphinoamide ligands

Popis výsledku v původním jazyce

[AuCl{RC(O)NHPPh2-κP}]gold(I) complexes with varying amide substituents (R = Me, Ph and ferrocenyl) were prepared, characterized by elemental analysis and spectroscopic methods (mass spectrometry and multinuclear NMR and IR spectroscopy) and further studied by single-crystal X-ray crystallography with a particular focus on solid-state interactions. In all cases, the crystal assembly was based mainly on conventional hydrogen bonds between the amide moieties. However, while in chloroform-solvated [AuCl{MeC(O)NHPPh2-κP}], these interactions were supported by pi center dot center dot center dot pi stacking of aromatic rings, in the crystal structures of the complexes bearing phenyl and ferrocenyl substituents, they cooperated with aurophilic interactions of the Au(I) centers, which in turn affected the C = O center dot center dot center dot HN hydrogen bonds.

Název v anglickém jazyce

Intermolecular interactions in the crystal structures of chlorogold(I) complexes with N-phosphinoamide ligands

Popis výsledku anglicky

[AuCl{RC(O)NHPPh2-κP}]gold(I) complexes with varying amide substituents (R = Me, Ph and ferrocenyl) were prepared, characterized by elemental analysis and spectroscopic methods (mass spectrometry and multinuclear NMR and IR spectroscopy) and further studied by single-crystal X-ray crystallography with a particular focus on solid-state interactions. In all cases, the crystal assembly was based mainly on conventional hydrogen bonds between the amide moieties. However, while in chloroform-solvated [AuCl{MeC(O)NHPPh2-κP}], these interactions were supported by pi center dot center dot center dot pi stacking of aromatic rings, in the crystal structures of the complexes bearing phenyl and ferrocenyl substituents, they cooperated with aurophilic interactions of the Au(I) centers, which in turn affected the C = O center dot center dot center dot HN hydrogen bonds.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA19-09334S" target="_blank" >GA19-09334S: Nekonvenční ferrocenové fosfiny</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

—

Svazek periodika

516

Číslo periodika v rámci svazku

February

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

5

Strana od-do

120138

Kód UT WoS článku

000605617600006

EID výsledku v databázi Scopus

2-s2.0-85096511120