Mechanical Impact of Heterogeneously Distributed H2O on Quartz Deformation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F24%3A10486747" target="_blank" >RIV/00216208:11310/24:10486747 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=vGI1ihW5Rq" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=vGI1ihW5Rq</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1029/2023JB027566" target="_blank" >10.1029/2023JB027566</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Mechanical Impact of Heterogeneously Distributed H2O on Quartz Deformation

Popis výsledku v původním jazyce

In order to identify relations between mechanical behavior, deformation mechanisms, microstructural properties, and H2O distribution, Tana-quartzite samples with added H2O ranging from 0 to 0.5 wt.% were deformed by axial shortening at constant displacement rates, at 900 degrees C and 1 GPa, reaching up to similar to 30% bulk strain. Samples with lower quantities of added H2O (0.1 and 0.2 wt.%) were in average similar to 30 MPa weaker than the as-is samples with no added H2O. In contrast, samples with more than 0.2 wt.% added H2O revealed more variable mechanical behavior, showing either weaker or stronger trend. The weaker samples showed strain localization in their central parts in the vicinity of the thermocouple, that is, the hottest parts of the samples, whereas the stronger samples showed localization in their upper, slightly colder parts. Bulk deformation is accommodated by crystal plasticity and dissolution-precipitation processes. Distribution of H2O in our samples revealed systematic decrease of H2O content in the interiors of original grains, caused by increasing strain and H2O draining into grain boundary regions. With increasing content of added H2O, the quartz recrystallization gradually changes from subgrain-rotation-dominated to crack-induced nucleation, along with increasing quantity of melt/fluid pockets. The unexpected strain localization in the upper parts of stronger samples most likely results from mode-1-cracking that led to drainage of grain boundaries (GB) due to the crack dilatancy effect, and inhibited dissolution-precipitation in the hottest part of the samples next to the thermocouple. The locus of deformation is then shifted to colder regions where more H2O is available along GB. Plain Language Summary The mechanical behavior of rocks is reflected by deformation microstructures, and it is usually dependent on available H2O in the deformation environment. We tested influence of H2O in quartzite samples by adding various amounts of H2O prior to deformation experiments, in the range from 0 to 0.5 wt.%. The results showed that samples with up to 0.2 wt.% of added H2O are generally weaker than the as-is samples, while with H2O addition of more than 0.2 wt.% mechanical behavior becomes more erratic. These samples showed either weaker or stronger behavior. While plastic deformation in weaker samples is localized mostly in sample regions with the highest temperature, deformation in stronger samples is unexpectedly localized in colder regions. Quartz grains are found to release initially present H2O from their interiors into grain boundary regions during deformation. Changes in mechanical properties with increasing content of H2O are closely related with changes in recrystallization processes. The unexpected localization of deformation in the colder regions results from drainage of GB due to the crack dilatancy effect. In the resulting dried GB, the dissolution-precipitation processes would be impeded, while the locus of deformation is shifted to colder parts with more H2O along the GB.

Název v anglickém jazyce

Mechanical Impact of Heterogeneously Distributed H2O on Quartz Deformation

Popis výsledku anglicky

In order to identify relations between mechanical behavior, deformation mechanisms, microstructural properties, and H2O distribution, Tana-quartzite samples with added H2O ranging from 0 to 0.5 wt.% were deformed by axial shortening at constant displacement rates, at 900 degrees C and 1 GPa, reaching up to similar to 30% bulk strain. Samples with lower quantities of added H2O (0.1 and 0.2 wt.%) were in average similar to 30 MPa weaker than the as-is samples with no added H2O. In contrast, samples with more than 0.2 wt.% added H2O revealed more variable mechanical behavior, showing either weaker or stronger trend. The weaker samples showed strain localization in their central parts in the vicinity of the thermocouple, that is, the hottest parts of the samples, whereas the stronger samples showed localization in their upper, slightly colder parts. Bulk deformation is accommodated by crystal plasticity and dissolution-precipitation processes. Distribution of H2O in our samples revealed systematic decrease of H2O content in the interiors of original grains, caused by increasing strain and H2O draining into grain boundary regions. With increasing content of added H2O, the quartz recrystallization gradually changes from subgrain-rotation-dominated to crack-induced nucleation, along with increasing quantity of melt/fluid pockets. The unexpected strain localization in the upper parts of stronger samples most likely results from mode-1-cracking that led to drainage of grain boundaries (GB) due to the crack dilatancy effect, and inhibited dissolution-precipitation in the hottest part of the samples next to the thermocouple. The locus of deformation is then shifted to colder regions where more H2O is available along GB. Plain Language Summary The mechanical behavior of rocks is reflected by deformation microstructures, and it is usually dependent on available H2O in the deformation environment. We tested influence of H2O in quartzite samples by adding various amounts of H2O prior to deformation experiments, in the range from 0 to 0.5 wt.%. The results showed that samples with up to 0.2 wt.% of added H2O are generally weaker than the as-is samples, while with H2O addition of more than 0.2 wt.% mechanical behavior becomes more erratic. These samples showed either weaker or stronger behavior. While plastic deformation in weaker samples is localized mostly in sample regions with the highest temperature, deformation in stronger samples is unexpectedly localized in colder regions. Quartz grains are found to release initially present H2O from their interiors into grain boundary regions during deformation. Changes in mechanical properties with increasing content of H2O are closely related with changes in recrystallization processes. The unexpected localization of deformation in the colder regions results from drainage of GB due to the crack dilatancy effect. In the resulting dried GB, the dissolution-precipitation processes would be impeded, while the locus of deformation is shifted to colder parts with more H2O along the GB.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10505 - Geology

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Geophysical Research: Solid Earth

ISSN

2169-9313

e-ISSN

2169-9356

Svazek periodika

129

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

32

Strana od-do

e2023JB027566

Kód UT WoS článku

001281212100001

EID výsledku v databázi Scopus

2-s2.0-85200109733