Binaphthyl Mediated Low Temperature Synthesis of Carbon Nitride Photocatalyst for Photocatalytic Hydrogen Evolution

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F24%3A10495982" target="_blank" >RIV/00216208:11310/24:10495982 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=Zrk~5NHE4h" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=Zrk~5NHE4h</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/cssc.202400618" target="_blank" >10.1002/cssc.202400618</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Binaphthyl Mediated Low Temperature Synthesis of Carbon Nitride Photocatalyst for Photocatalytic Hydrogen Evolution

Popis výsledku v původním jazyce

Metal-free graphitic carbon nitrides are on the rise as polymer photocatalysts under visible light illumination, taking shares in a range of promising photocatalytic reactions, including water splitting. Their simple synthesis and facile structural modification afford them exceptional tunability, enabling the creation of photocatalysts with distinct properties. While their metal-free nature marks a significant step towards environmental sustainability, the high energy consumption required to produce carbon nitride photocatalysts remains a substantial barrier to their widespread adoption. Furthermore, the process of condensation at approximately 550 degrees C typically results in solid yields of less than 15 %, significantly challenging their economic viability. Here, we report on lowering manufacturing conditions of carbon nitride photocatalysts whilst enhancing photocatalytic activity by introducing binaphthyl diamine as a structural mediator. At 450 degrees C in 2 hours, carbon nitride photocatalyst shows a lower bandgap and enables visible light induced hydrogen evolution (194 mu mol h-1) comparable to benchmark carbon nitride photocatalysts. Research in metal-free hydrogen generation using graphitic carbon nitride under visible light is promising but faces high temperature -low yield syntheses. This study introduces a method to synthesize photocatalytic carbon nitrides at 450 degrees C using binaphthyldiamine as a structural modifier, which enhances photocatalytic activity and solid yield by overcoming high energy synthesis requirement. image

Název v anglickém jazyce

Binaphthyl Mediated Low Temperature Synthesis of Carbon Nitride Photocatalyst for Photocatalytic Hydrogen Evolution

Popis výsledku anglicky

Metal-free graphitic carbon nitrides are on the rise as polymer photocatalysts under visible light illumination, taking shares in a range of promising photocatalytic reactions, including water splitting. Their simple synthesis and facile structural modification afford them exceptional tunability, enabling the creation of photocatalysts with distinct properties. While their metal-free nature marks a significant step towards environmental sustainability, the high energy consumption required to produce carbon nitride photocatalysts remains a substantial barrier to their widespread adoption. Furthermore, the process of condensation at approximately 550 degrees C typically results in solid yields of less than 15 %, significantly challenging their economic viability. Here, we report on lowering manufacturing conditions of carbon nitride photocatalysts whilst enhancing photocatalytic activity by introducing binaphthyl diamine as a structural mediator. At 450 degrees C in 2 hours, carbon nitride photocatalyst shows a lower bandgap and enables visible light induced hydrogen evolution (194 mu mol h-1) comparable to benchmark carbon nitride photocatalysts. Research in metal-free hydrogen generation using graphitic carbon nitride under visible light is promising but faces high temperature -low yield syntheses. This study introduces a method to synthesize photocatalytic carbon nitrides at 450 degrees C using binaphthyldiamine as a structural modifier, which enhances photocatalytic activity and solid yield by overcoming high energy synthesis requirement. image

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ChemSusChem

ISSN

1864-5631

e-ISSN

1864-564X

Svazek periodika

17

Číslo periodika v rámci svazku

22

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

6

Strana od-do

e202400618

Kód UT WoS článku

001280757700001

EID výsledku v databázi Scopus

2-s2.0-85200041422