Organic Salts Of Guanazole - Seeking For New Materials For Second Harmonic Generation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F13%3A10125734" target="_blank" >RIV/00216208:11320/13:10125734 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/13:00398268 RIV/00216208:11310/13:10125734

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molstruc.2012.11.011" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2012.11.011</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2012.11.011" target="_blank" >10.1016/j.molstruc.2012.11.011</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Organic Salts Of Guanazole - Seeking For New Materials For Second Harmonic Generation

Popis výsledku v původním jazyce

Four novel organic salts of 3,5-diamino-1,2,4-triazole (guanazole) with malonic, glutaric, adipic and L-malic acids have been prepared and X-ray structural analyses have been performed within our project focused on the preparation of new non-linear optical materials. The salts guanazolium(1+) hydrogen adipate and guanazolium(1+) hydrogen L-malate crystallize in the non-centrosymmetric space groups of monoclinic (Cc) and orthorhombic systems (P212121), respectively. Unfortunately, the remaining two saltsguanazolium(1+) hydrogen malonate and guanazolium(1+) hydrogen glutarate belong to the centrosymmetric space group P-1 of the triclinic system. All salts were also characterized by the methods of vibrational spectroscopy (FTIR and FT Raman). The interpretation of the vibrational spectra is based on our previous ab initio calculations. The second harmonic generation's quantitative measurements of powdered samples at 800 nm and 1064 nm were performed. The thermal behavior of the prepared

Název v anglickém jazyce

Organic Salts Of Guanazole - Seeking For New Materials For Second Harmonic Generation

Popis výsledku anglicky

Four novel organic salts of 3,5-diamino-1,2,4-triazole (guanazole) with malonic, glutaric, adipic and L-malic acids have been prepared and X-ray structural analyses have been performed within our project focused on the preparation of new non-linear optical materials. The salts guanazolium(1+) hydrogen adipate and guanazolium(1+) hydrogen L-malate crystallize in the non-centrosymmetric space groups of monoclinic (Cc) and orthorhombic systems (P212121), respectively. Unfortunately, the remaining two saltsguanazolium(1+) hydrogen malonate and guanazolium(1+) hydrogen glutarate belong to the centrosymmetric space group P-1 of the triclinic system. All salts were also characterized by the methods of vibrational spectroscopy (FTIR and FT Raman). The interpretation of the vibrational spectra is based on our previous ab initio calculations. The second harmonic generation's quantitative measurements of powdered samples at 800 nm and 1064 nm were performed. The thermal behavior of the prepared

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

—

Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

1044

Číslo periodika v rámci svazku

24 July 2013

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

239-247

Kód UT WoS článku

000320635200037

EID výsledku v databázi Scopus

—