Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F14%3A10159367" target="_blank" >RIV/00216208:11320/14:10159367 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/14:00427133 RIV/00216208:11310/14:10159367

Výsledek na webu

<a href="http://dx.doi.org/10.1039/C3CE42306A" target="_blank" >http://dx.doi.org/10.1039/C3CE42306A</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C3CE42306A" target="_blank" >10.1039/C3CE42306A</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties

Popis výsledku v původním jazyce

Eight inorganic salts of 2-amino-1,3,4-thiadiazole (2-athd) with hydrochloric, perchloric, nitric, sulphuric, selenic, phosphorous and phosphoric acids were prepared, and their crystal structures were determined. Seven of the compounds crystallise in monoclinic space groups - i.e., 2-athd(1+) chloride monohydrate (P21/c), 2-athd(1+) selenate monohydrate (Pc), 2- athd(1+) dihydrogen phosphate (Cc), 2-athd(1+) phosphite (P21/a), 2-athd(1+) nitrate (P21/c), 2-athd(1+) 2-athd perchlorate (P21/n) and 2-athd(1+) perchlorate (P21/c) - and one crystallises in an orthorhombic space group - 2-athd(1+) hydrogen sulphate (P212121). The thermal behaviours of the materials were studied (DSC) down to liquid nitrogen temperature, and the properties of the perchlorates, hydrogen sulphate and selenate monohydrate crystals were discussed with respect to the results of high or low-temperature X-ray diffraction, IR and Raman spectroscopic study. Quantitative measurements of the second harmonic generation o

Název v anglickém jazyce

Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties

Popis výsledku anglicky

Eight inorganic salts of 2-amino-1,3,4-thiadiazole (2-athd) with hydrochloric, perchloric, nitric, sulphuric, selenic, phosphorous and phosphoric acids were prepared, and their crystal structures were determined. Seven of the compounds crystallise in monoclinic space groups - i.e., 2-athd(1+) chloride monohydrate (P21/c), 2-athd(1+) selenate monohydrate (Pc), 2- athd(1+) dihydrogen phosphate (Cc), 2-athd(1+) phosphite (P21/a), 2-athd(1+) nitrate (P21/c), 2-athd(1+) 2-athd perchlorate (P21/n) and 2-athd(1+) perchlorate (P21/c) - and one crystallises in an orthorhombic space group - 2-athd(1+) hydrogen sulphate (P212121). The thermal behaviours of the materials were studied (DSC) down to liquid nitrogen temperature, and the properties of the perchlorates, hydrogen sulphate and selenate monohydrate crystals were discussed with respect to the results of high or low-temperature X-ray diffraction, IR and Raman spectroscopic study. Quantitative measurements of the second harmonic generation o

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

CrystEngComm

ISSN

1466-8033

e-ISSN

—

Svazek periodika

16

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

14

Strana od-do

1763-1776

Kód UT WoS článku

000331175900022

EID výsledku v databázi Scopus

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