Influence of mechanical activation on DC conductivity of kaolin

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F18%3A10388650" target="_blank" >RIV/00216208:11320/18:10388650 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389021:_____/18:00498237 RIV/68407700:21110/18:00328175

Výsledek na webu

<a href="https://doi.org/10.1016/j.clay.2017.12.038" target="_blank" >https://doi.org/10.1016/j.clay.2017.12.038</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.clay.2017.12.038" target="_blank" >10.1016/j.clay.2017.12.038</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Influence of mechanical activation on DC conductivity of kaolin

Popis výsledku v původním jazyce

In this study, the effect of dry milling of kaolin (92 mass% of kaolinite) on its physical properties and microstructure development during firing was investigated using thermal analyses, X-ray diffraction, scanning electron microscopy, and DC conductivity measurements. X-ray diffraction showed a decrease in the intensity of reflections of kaolinite with rising milling time. Moreover, formation of agglomerates from kaolinite particles was observed. A longer milling time led to a lower dehydroxylation temperature and contributed to a more substantial overall contraction of samples. After dehydroxylation, the relative bulk density increased with an increasing milling time. Below the temperature 450 degrees C (start of dehydroxylation), the highest values of the DC conductivity of raw samples were observed for the longest milling times. The main charge carriers are the H+ and OH- ions, originated from dissociation of the adsorbed water and from the coordinated water that was formed during mechanical dehydroxylation of kaolinite, complemented with alkali ions Na+ and K+ which are present as impurities in kaolin. The presence of coordinated water was proven by increasing values of the DC conductivity and by decreasing values of conduction activation energy from 1.73 eV to 0.85 eV with increasing milling time. A similar trend of conduction activation energy was observed in the temperature range 650-750 degrees C, where the values of conduction activation energy changed from 0.79 eV to 0.52 eV with increasing milling time. After dehydroxylation (above 750 degrees C), the DC conductivity of raw samples slightly decreased with increasing milling time.

Název v anglickém jazyce

Influence of mechanical activation on DC conductivity of kaolin

Popis výsledku anglicky

In this study, the effect of dry milling of kaolin (92 mass% of kaolinite) on its physical properties and microstructure development during firing was investigated using thermal analyses, X-ray diffraction, scanning electron microscopy, and DC conductivity measurements. X-ray diffraction showed a decrease in the intensity of reflections of kaolinite with rising milling time. Moreover, formation of agglomerates from kaolinite particles was observed. A longer milling time led to a lower dehydroxylation temperature and contributed to a more substantial overall contraction of samples. After dehydroxylation, the relative bulk density increased with an increasing milling time. Below the temperature 450 degrees C (start of dehydroxylation), the highest values of the DC conductivity of raw samples were observed for the longest milling times. The main charge carriers are the H+ and OH- ions, originated from dissociation of the adsorbed water and from the coordinated water that was formed during mechanical dehydroxylation of kaolinite, complemented with alkali ions Na+ and K+ which are present as impurities in kaolin. The presence of coordinated water was proven by increasing values of the DC conductivity and by decreasing values of conduction activation energy from 1.73 eV to 0.85 eV with increasing milling time. A similar trend of conduction activation energy was observed in the temperature range 650-750 degrees C, where the values of conduction activation energy changed from 0.79 eV to 0.52 eV with increasing milling time. After dehydroxylation (above 750 degrees C), the DC conductivity of raw samples slightly decreased with increasing milling time.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

<a href="/cs/project/GBP105%2F12%2FG059" target="_blank" >GBP105/12/G059: Kumulativní časově závislé procesy ve stavebních materiálech a konstrukcích</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Applied Clay Science

ISSN

0169-1317

e-ISSN

—

Svazek periodika

154

Číslo periodika v rámci svazku

154

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

7

Strana od-do

36-42

Kód UT WoS článku

000424722900005

EID výsledku v databázi Scopus

2-s2.0-85039718270