Identification of ferric oxide polymorphs in nanoparticles prepared by sol-gel method and maximization of epsilon-Fe2O3 content
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F19%3A10388239" target="_blank" >RIV/00216208:11320/19:10388239 - isvavai.cz</a>
Výsledek na webu
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=FdoIiIeW2o" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=FdoIiIeW2o</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jmmm.2018.09.107" target="_blank" >10.1016/j.jmmm.2018.09.107</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Identification of ferric oxide polymorphs in nanoparticles prepared by sol-gel method and maximization of epsilon-Fe2O3 content
Popis výsledku v původním jazyce
The effects of annealing temperature (1000-1125 degrees C) and Fe2O3 mass fraction (0.3-0.5) in the initial mixture on the composition of ferric oxide polymorphs within the Fe2O3/SiO2 nanocomposite prepared by sol-gel method were investigated. The structural and magnetic properties of prepared samples were characterized in detail by combination of X-ray powder diffraction (XRPD), high-resolution transmission electron microscopy, magnetic measurements and a local probe technique - transmission Mossbauer spectroscopy (TMS). The optimal conditions for preparation of epsilon-Fe2O3 rich sample were established and similar to 91% of the epsilon-phase was reached with the characteristic particle diameter of 25 nm. It was observed that with increasing mass fraction of Fe2O3 in the starting material, the optimal annealing temperature decreases, while the width of the particle size distribution tends to increase. The relative concentrations of the four present polymorphs derived from XRD and TMS are in very good mutual agreement.
Název v anglickém jazyce
Identification of ferric oxide polymorphs in nanoparticles prepared by sol-gel method and maximization of epsilon-Fe2O3 content
Popis výsledku anglicky
The effects of annealing temperature (1000-1125 degrees C) and Fe2O3 mass fraction (0.3-0.5) in the initial mixture on the composition of ferric oxide polymorphs within the Fe2O3/SiO2 nanocomposite prepared by sol-gel method were investigated. The structural and magnetic properties of prepared samples were characterized in detail by combination of X-ray powder diffraction (XRPD), high-resolution transmission electron microscopy, magnetic measurements and a local probe technique - transmission Mossbauer spectroscopy (TMS). The optimal conditions for preparation of epsilon-Fe2O3 rich sample were established and similar to 91% of the epsilon-phase was reached with the characteristic particle diameter of 25 nm. It was observed that with increasing mass fraction of Fe2O3 in the starting material, the optimal annealing temperature decreases, while the width of the particle size distribution tends to increase. The relative concentrations of the four present polymorphs derived from XRD and TMS are in very good mutual agreement.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Návaznosti výsledku
Projekt
<a href="/cs/project/GA16-04340S" target="_blank" >GA16-04340S: Oxidové nanomagnety, jejich vlastnosti a interakce s biologickými systémy</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2019
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Magnetism and Magnetic Materials
ISSN
0304-8853
e-ISSN
—
Svazek periodika
472
Číslo periodika v rámci svazku
October 2018
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
8
Strana od-do
96-103
Kód UT WoS článku
000449681300015
EID výsledku v databázi Scopus
2-s2.0-85054663198