Electrochemical activity of the polycrystalline cerium oxide films for hydrogen peroxide detection

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F19%3A10395970" target="_blank" >RIV/00216208:11320/19:10395970 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=aa5mliVC~u" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=aa5mliVC~u</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.apsusc.2019.05.205" target="_blank" >10.1016/j.apsusc.2019.05.205</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electrochemical activity of the polycrystalline cerium oxide films for hydrogen peroxide detection

Popis výsledku v původním jazyce

Polycrystalline cerium oxide thin films (15 nm) deposited on a glassy carbon substrate were used as an electrode in a mediator-free, non-enzymatic electrochemical sensor for hydrogen peroxide. The electrode surface was characterized by X-ray photoelectron spectroscopy, resonant photoelectron spectroscopy, scanning electron microscopy and atomic force microscopy. The electrode sensitivity, detection limit and pH range of sensor stability were determined by applying electrochemical techniques: cyclic voltammetry and chronoamperometry. It was found that the sensor reactivity to H2O2 is directly related to the presence of electroactive cerium centres of 3+ character on the electrode surface. The Michaelis-Menten mechanism of catalase-like activity of ceria film is suggested as an explanation of the data and discussed. The results confirmed the sensing abilities of technologically well-accessible nanostructured cerium oxide films for hydrogen peroxide detection without using a mediator, i.e. the enzymatic properties of CeO2/GC electrode.

Název v anglickém jazyce

Electrochemical activity of the polycrystalline cerium oxide films for hydrogen peroxide detection

Popis výsledku anglicky

Polycrystalline cerium oxide thin films (15 nm) deposited on a glassy carbon substrate were used as an electrode in a mediator-free, non-enzymatic electrochemical sensor for hydrogen peroxide. The electrode surface was characterized by X-ray photoelectron spectroscopy, resonant photoelectron spectroscopy, scanning electron microscopy and atomic force microscopy. The electrode sensitivity, detection limit and pH range of sensor stability were determined by applying electrochemical techniques: cyclic voltammetry and chronoamperometry. It was found that the sensor reactivity to H2O2 is directly related to the presence of electroactive cerium centres of 3+ character on the electrode surface. The Michaelis-Menten mechanism of catalase-like activity of ceria film is suggested as an explanation of the data and discussed. The results confirmed the sensing abilities of technologically well-accessible nanostructured cerium oxide films for hydrogen peroxide detection without using a mediator, i.e. the enzymatic properties of CeO2/GC electrode.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10305 - Fluids and plasma physics (including surface physics)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Applied Surface Science

ISSN

0169-4332

e-ISSN

—

Svazek periodika

488

Číslo periodika v rámci svazku

15 Sep

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

351-359

Kód UT WoS článku

000472476200039

EID výsledku v databázi Scopus

2-s2.0-85066441759