Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F20%3A10423247" target="_blank" >RIV/00216208:11320/20:10423247 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=PucfJpZevD" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=PucfJpZevD</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jpcs.2020.109609" target="_blank" >10.1016/j.jpcs.2020.109609</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Popis výsledku v původním jazyce

We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F-SnO2 (FTO) glass. Annealing was carried out at 500 degrees C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO(2 )nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes&apos; surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.

Název v anglickém jazyce

Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Popis výsledku anglicky

We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F-SnO2 (FTO) glass. Annealing was carried out at 500 degrees C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO(2 )nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes&apos; surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10305 - Fluids and plasma physics (including surface physics)

Projekt

<a href="/cs/project/EF16_013%2F0001788" target="_blank" >EF16_013/0001788: Laboratoř fyziky povrchů - Optická dráha pro výzkum materiálů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Physics and Chemistry of Solids

ISSN

0022-3697

e-ISSN

—

Svazek periodika

147

Číslo periodika v rámci svazku

Dec

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

109609

Kód UT WoS článku

000567084700005

EID výsledku v databázi Scopus

2-s2.0-85088148922