Robust intralayer antiferromagnetism and tricriticality in the van der Waals compound VBr3
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F23%3A10469459" target="_blank" >RIV/00216208:11320/23:10469459 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/00216208:11310/23:10469459
Výsledek na webu
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=_c0t7AHJzw" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=_c0t7AHJzw</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1103/PhysRevB.108.104416" target="_blank" >10.1103/PhysRevB.108.104416</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Robust intralayer antiferromagnetism and tricriticality in the van der Waals compound VBr3
Popis výsledku v původním jazyce
We studied magnetic states and phase transitions in the van der Waals antiferromagnet VBr3 experimentally by specific heat and magnetization measurements of single crystals in high magnetic fields and theoretically by the density functional theory calculations focused on exchange interactions. The magnetization behavior mimics Ising antiferromagnets with magnetic moments pointing out-of-plane due to strong uniaxial magnetocrystalline anisotropy. The out-of-plane magnetic field induces a spin-flip metamagnetic transition of first-order type at low temperatures, while at higher temperatures, the transition becomes continuous. The first-order and continuous transition segments in the field-temperature phase diagram meet at a tricritical point. The magnetization response to the in-plane field manifests a continuous spin canting which is completed at the anisotropy field μ(0)H(MA) = 27T. At higher fields, the two magnetization curves above saturate at the same value of magnetic moment μ(sat) = 1.2μ(B)/f.u., which is much smaller than the spin-only (S=1) moment of the V(3+) ion. The reduced moment can be explained by the existence of an unquenched orbital magnetic moment antiparallel to the spin. The orbital moment is a key ingredient of a mechanism responsible for the observed large anisotropy. The exact energy evaluation of possible magnetic structures shows that the intralayer zigzag antiferromagnetic (AFM) order is preferred, which renders the AFM ground state significantly more stable against the spin-flip transition than the other options. The calculations also predict that a minimal distortion of the Br ion sublattice causes a radical change of the orbital occupation in the ground state, connected with the formation of the orbital moment and the stability of magnetic order.
Název v anglickém jazyce
Robust intralayer antiferromagnetism and tricriticality in the van der Waals compound VBr3
Popis výsledku anglicky
We studied magnetic states and phase transitions in the van der Waals antiferromagnet VBr3 experimentally by specific heat and magnetization measurements of single crystals in high magnetic fields and theoretically by the density functional theory calculations focused on exchange interactions. The magnetization behavior mimics Ising antiferromagnets with magnetic moments pointing out-of-plane due to strong uniaxial magnetocrystalline anisotropy. The out-of-plane magnetic field induces a spin-flip metamagnetic transition of first-order type at low temperatures, while at higher temperatures, the transition becomes continuous. The first-order and continuous transition segments in the field-temperature phase diagram meet at a tricritical point. The magnetization response to the in-plane field manifests a continuous spin canting which is completed at the anisotropy field μ(0)H(MA) = 27T. At higher fields, the two magnetization curves above saturate at the same value of magnetic moment μ(sat) = 1.2μ(B)/f.u., which is much smaller than the spin-only (S=1) moment of the V(3+) ion. The reduced moment can be explained by the existence of an unquenched orbital magnetic moment antiparallel to the spin. The orbital moment is a key ingredient of a mechanism responsible for the observed large anisotropy. The exact energy evaluation of possible magnetic structures shows that the intralayer zigzag antiferromagnetic (AFM) order is preferred, which renders the AFM ground state significantly more stable against the spin-flip transition than the other options. The calculations also predict that a minimal distortion of the Br ion sublattice causes a radical change of the orbital occupation in the ground state, connected with the formation of the orbital moment and the stability of magnetic order.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2023
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Physical Review B
ISSN
2469-9950
e-ISSN
2469-9969
Svazek periodika
108
Číslo periodika v rámci svazku
10
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
10
Strana od-do
104416
Kód UT WoS článku
001107723400002
EID výsledku v databázi Scopus
2-s2.0-85172682388