Novel technique to produce porous thermochromic VO2 nanoparticle films using gas aggregation source

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F25%3A10503766" target="_blank" >RIV/00216208:11320/25:10503766 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=25adDskFgk" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=25adDskFgk</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1038/s41598-025-86272-9" target="_blank" >10.1038/s41598-025-86272-9</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Novel technique to produce porous thermochromic VO2 nanoparticle films using gas aggregation source

Popis výsledku v původním jazyce

Vanadium dioxide (VO2) is a phase transition material that undergoes semiconductor-to-metal transition at the temperature of about 68 degrees C. This extraordinary feature triggered intensive research focused on the controlled synthesis of VO2. In this study, we introduce and investigate an original linker- and solvent-free strategy enabling the production of highly porous VO2 nanoparticle-based films. This technique combines a gas-phase synthesis of vanadium nanoparticles and their subsequent atmospheric pressure thermal oxidation. It is shown that the thermochromic behaviour of such produced nanomaterial is at the fixed oxidation temperature strongly dependent on the oxidation time. Concerning this, it was found that there exists an optimal oxidation time (60 s in our study) that assures the production of crystalline VO2 nanoparticles with the highest, reproducible and temporally stable semiconductor-to-metal transition with the resistive switching ratio close to 2 orders of magnitude and dramatic switching of optical properties in the near infra-red spectral region.

Název v anglickém jazyce

Novel technique to produce porous thermochromic VO2 nanoparticle films using gas aggregation source

Popis výsledku anglicky

Vanadium dioxide (VO2) is a phase transition material that undergoes semiconductor-to-metal transition at the temperature of about 68 degrees C. This extraordinary feature triggered intensive research focused on the controlled synthesis of VO2. In this study, we introduce and investigate an original linker- and solvent-free strategy enabling the production of highly porous VO2 nanoparticle-based films. This technique combines a gas-phase synthesis of vanadium nanoparticles and their subsequent atmospheric pressure thermal oxidation. It is shown that the thermochromic behaviour of such produced nanomaterial is at the fixed oxidation temperature strongly dependent on the oxidation time. Concerning this, it was found that there exists an optimal oxidation time (60 s in our study) that assures the production of crystalline VO2 nanoparticles with the highest, reproducible and temporally stable semiconductor-to-metal transition with the resistive switching ratio close to 2 orders of magnitude and dramatic switching of optical properties in the near infra-red spectral region.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10301 - Atomic, molecular and chemical physics (physics of atoms and molecules including collision, interaction with radiation, magnetic resonances, Mössbauer effect)

Projekt

<a href="/cs/project/GA22-16667S" target="_blank" >GA22-16667S: Syntéza nanomateriálů na bázi oxidů kovů pro povrchem zesílenou Ramanovu spektroskopii pomocí plazmových plynně agregačních zdrojů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Scientific Reports

ISSN

2045-2322

e-ISSN

2045-2322

Svazek periodika

15

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

1755

Kód UT WoS článku

001395411300004

EID výsledku v databázi Scopus

2-s2.0-85215358066