Identifikace při eleminační voltametrii s lineárním skenem

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F05%3A00014626" target="_blank" >RIV/00216224:14310/05:00014626 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Identification of current nature by elimination voltammetry with linear scan

Popis výsledku v původním jazyce

This paper is devoted to the detailed description of mathematical procedures used in the elimination voltammetry with linear scan (EVLS), and their applications to the identification of current nature. It has been shown that the EVLS, based on an elimination function generated from total currents measured at different scan rates, is widely applicable in electrochemistry. The current nature can be identified from the different course of selected elimination functions, i.e., the dependence of the currentelimination coefficient beta(EVLS) on the scan rate coefficient x (see Fig. 1). This approach has been tested by studying the reduction processes of azidothymidine (AZT), Pb(II), and Cd(II) on a hanging mercury drop electrode (HMDE). In addition the calculation of elimination function conserving the diffusion current (I-d) and eliminating kinetic and charging currents (I-k, I-c) for an adsorbed electroactive substance has been presented. This elimination providing the peak-counterpeak si

Název v anglickém jazyce

Identification of current nature by elimination voltammetry with linear scan

Popis výsledku anglicky

This paper is devoted to the detailed description of mathematical procedures used in the elimination voltammetry with linear scan (EVLS), and their applications to the identification of current nature. It has been shown that the EVLS, based on an elimination function generated from total currents measured at different scan rates, is widely applicable in electrochemistry. The current nature can be identified from the different course of selected elimination functions, i.e., the dependence of the currentelimination coefficient beta(EVLS) on the scan rate coefficient x (see Fig. 1). This approach has been tested by studying the reduction processes of azidothymidine (AZT), Pb(II), and Cd(II) on a hanging mercury drop electrode (HMDE). In addition the calculation of elimination function conserving the diffusion current (I-d) and eliminating kinetic and charging currents (I-k, I-c) for an adsorbed electroactive substance has been presented. This elimination providing the peak-counterpeak si

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CG - Elektrochemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2005

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

ISSN

0022-0728

e-ISSN

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Svazek periodika

582

Číslo periodika v rámci svazku

1-2

Stát vydavatele periodika

CZ - Česká republika

Počet stran výsledku

9

Strana od-do

258-266

Kód UT WoS článku

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EID výsledku v databázi Scopus

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