Phosphoric ligands immobilized on polymeric resins

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00025415" target="_blank" >RIV/00216224:14310/08:00025415 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

čeština

Název v původním jazyce

Phosphoric ligands immobilized on polymeric resins

Popis výsledku v původním jazyce

Hydrogen cyanide (HCN) addition is chemical reaction taking important part in chemical industry over the world. HCN addition reactions are one the most used synthetic routes leading to cyano compounds which are indispensable materials for pharmaceuticalindustry and chemical industry itself as well. The key role in HCN additions is represented by the catalytic system present in reaction mixtures, which increases yields and purity of desired product and decreases energetic and material demands of the reaction at the same time. It is known that Ni(0)-complexes stand as the most used catalysts in such mixtures having high efficiency and selectivity, although catalytic system may be rather complicated and the resulting product can be dependent on many factors. Some disadvantages of such homogenous catalytic systems could be eliminated using immobilized Ni-complexes as catalysts. First step in this approach is to prepare phosphoric ligands immobilized on suitable polymeric resin.

Název v anglickém jazyce

Phosphoric ligands immobilized on polymeric resins

Popis výsledku anglicky

Hydrogen cyanide (HCN) addition is chemical reaction taking important part in chemical industry over the world. HCN addition reactions are one the most used synthetic routes leading to cyano compounds which are indispensable materials for pharmaceuticalindustry and chemical industry itself as well. The key role in HCN additions is represented by the catalytic system present in reaction mixtures, which increases yields and purity of desired product and decreases energetic and material demands of the reaction at the same time. It is known that Ni(0)-complexes stand as the most used catalysts in such mixtures having high efficiency and selectivity, although catalytic system may be rather complicated and the resulting product can be dependent on many factors. Some disadvantages of such homogenous catalytic systems could be eliminated using immobilized Ni-complexes as catalysts. First step in this approach is to prepare phosphoric ligands immobilized on suitable polymeric resin.

Druh

D - Stať ve sborníku

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/2A-1TP1%2F090" target="_blank" >2A-1TP1/090: Nové katalyzátory a činidla pro udržitelné zelené syntézy a kombinatoriální syntézy.</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2008

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

ECSOC 12: http://www.usc.es/congresos/ecsoc/12/ECSOC12.htm; CD version

ISBN

3-906980-20-0

ISSN

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e-ISSN

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Počet stran výsledku

7

Strana od-do

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Název nakladatele

Molecular Diversity Preservation International (MDPI), Kandererstrasse 25, CH-4057 Basel, Switzerland

Místo vydání

Basel, Switzerland

Místo konání akce

http://www.usc.es/congresos/ecsoc/12/ECSOC12.htm

Datum konání akce

11. 1. 2008

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

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