WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00027896" target="_blank" >RIV/00216224:14310/08:00027896 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
Popis výsledku v původním jazyce
Enantiomeric fractions (EF) of PCB 95, 132, 149, and 174, alpha-HCH, o,p'-DDD, and o,p'-DDT were analyzed in 112 soil samples using two-dimensional gas chromatography and triple-quadrupole mass spectrometry. To assess the soil conditions that facilitateenantioselective fractionation of chiral compounds, EF values of selected PCBs were further correlated with a wide range of physicochemical and microbial soil parameters in an attempt to identify the influential factors and their mutual relations. It wasevident that soils where nonracemic ratios of investigated compounds were found were more carbon rich but they also contained significantly more humic and fulvic acids and total nitrogen. These specific physicochemical properties were accompanied by significantly increased values of all key biotic variables, the amount of microbial biomass, and its respiration activity (both basal and substrate-induced). Therefore, the shifts from racemic ratios appeared to be associated with more susta
Název v anglickém jazyce
WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
Popis výsledku anglicky
Enantiomeric fractions (EF) of PCB 95, 132, 149, and 174, alpha-HCH, o,p'-DDD, and o,p'-DDT were analyzed in 112 soil samples using two-dimensional gas chromatography and triple-quadrupole mass spectrometry. To assess the soil conditions that facilitateenantioselective fractionation of chiral compounds, EF values of selected PCBs were further correlated with a wide range of physicochemical and microbial soil parameters in an attempt to identify the influential factors and their mutual relations. It wasevident that soils where nonracemic ratios of investigated compounds were found were more carbon rich but they also contained significantly more humic and fulvic acids and total nitrogen. These specific physicochemical properties were accompanied by significantly increased values of all key biotic variables, the amount of microbial biomass, and its respiration activity (both basal and substrate-induced). Therefore, the shifts from racemic ratios appeared to be associated with more susta
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
DK - Kontaminace a dekontaminace půdy včetně pesticidů
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2008
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Organohalogen Compounds
ISSN
1026-4892
e-ISSN
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Svazek periodika
2008
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
200
Strana od-do
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Kód UT WoS článku
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EID výsledku v databázi Scopus
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