Calibration of the silicon rubber passive samplers: Relating sampling rate to hydrophobicity.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F10%3A00043444" target="_blank" >RIV/00216224:14310/10:00043444 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Calibration of the silicon rubber passive samplers: Relating sampling rate to hydrophobicity.

Popis výsledku v původním jazyce

Using a new concept sampling rates (Rs) for silicone rubber (SR) passive samplers could be measured without the necessity to analyse aqueous phase concentrations. SR sheets of the large total surface area spiked with polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were applied as a dosing system. SR uptake sheets of much smaller surface were used to measure the uptake rate. For two experiments under largely different hydrodynamic conditions decreasing log linear relations ofRs with hydrophobicity and diffusion coefficients in water were found. The slopes were equal and the difference in exposure conditions was characterized by different intercepts. For extrapolation of Rs to higher hydrophobicity range an empirical model based on passive sampler-water partition coefficients (Kpw) was derived showing a good agreement with a theoretical model based on diffusion coefficients.

Název v anglickém jazyce

Calibration of the silicon rubber passive samplers: Relating sampling rate to hydrophobicity.

Popis výsledku anglicky

Using a new concept sampling rates (Rs) for silicone rubber (SR) passive samplers could be measured without the necessity to analyse aqueous phase concentrations. SR sheets of the large total surface area spiked with polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were applied as a dosing system. SR uptake sheets of much smaller surface were used to measure the uptake rate. For two experiments under largely different hydrodynamic conditions decreasing log linear relations ofRs with hydrophobicity and diffusion coefficients in water were found. The slopes were equal and the difference in exposure conditions was characterized by different intercepts. For extrapolation of Rs to higher hydrophobicity range an empirical model based on passive sampler-water partition coefficients (Kpw) was derived showing a good agreement with a theoretical model based on diffusion coefficients.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

DJ - Znečištění a kontrola vody

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Environmental Science & Technology

ISSN

0013-936X

e-ISSN

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Svazek periodika

44/2010

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

6

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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