Aluminum(III) chloride-alkoxides as molecular precursors for alumina

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00049935" target="_blank" >RIV/00216224:14310/11:00049935 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Aluminum(III) chloride-alkoxides as molecular precursors for alumina

Popis výsledku v původním jazyce

The reactions of dichloroethylalane with selected alcohols and phenols afforded a series of six new crystalline aliminum(III) chloride-alkoxides which were structurally characterized by the single crystal X-ray diffraction analysis. The prepared molecules display, depending on the steric properties of employed substituents and the reaction and crystallization conditions, a large structural variability. These compounds are by virtue of their composition suitable single-source precursors for alumina. Therefore the transformations of aluminum(III) chloride-alkoxides to aluminum(III) oxide was performed by solution thermolysis in a high-boiling solvent. The reactions are based on alkylhalide elimination which was proved by indentifying byproducts by gas chromatography-mass spectrometry.

Název v anglickém jazyce

Aluminum(III) chloride-alkoxides as molecular precursors for alumina

Popis výsledku anglicky

The reactions of dichloroethylalane with selected alcohols and phenols afforded a series of six new crystalline aliminum(III) chloride-alkoxides which were structurally characterized by the single crystal X-ray diffraction analysis. The prepared molecules display, depending on the steric properties of employed substituents and the reaction and crystallization conditions, a large structural variability. These compounds are by virtue of their composition suitable single-source precursors for alumina. Therefore the transformations of aluminum(III) chloride-alkoxides to aluminum(III) oxide was performed by solution thermolysis in a high-boiling solvent. The reactions are based on alkylhalide elimination which was proved by indentifying byproducts by gas chromatography-mass spectrometry.

Druh

O - Ostatní výsledky

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů