Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00054608" target="_blank" >RIV/00216224:14310/11:00054608 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00000493:G41__/11:#0000387

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.electacta.2011.09.019" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2011.09.019</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.electacta.2011.09.019" target="_blank" >10.1016/j.electacta.2011.09.019</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars

Popis výsledku v původním jazyce

Ferroceneboronic acid (FcBA) was used as a redox-active probe suitable for monitoring of diol-boronate interactions. Voltammetric and amperometric measurements allowed to detect FcBA forms - free and bound in the boronate complex. In this way, the complexation interaction was studied for a set of saccharide molecules as model diols and the corresponding affinity equilibrium constants were determined. A shift of the peak potential on voltammograms accompanying formation of the boronate complex with FcBAwas proposed as a probe for electrochemical characterization of surface-confined diol-containing structures. The model experiments were carried out using sorbitol- and 1,6-hexandiol-modified polyepichlorhydrin conjugates deposited on the electrodes; theformer compound was able to form the boronate complex while no change of the peak potential for the latter conjugate was observed.

Název v anglickém jazyce

Ferroceneboronic Acid for the Electrochemical Probing of Interactions Involving Sugars

Popis výsledku anglicky

Ferroceneboronic acid (FcBA) was used as a redox-active probe suitable for monitoring of diol-boronate interactions. Voltammetric and amperometric measurements allowed to detect FcBA forms - free and bound in the boronate complex. In this way, the complexation interaction was studied for a set of saccharide molecules as model diols and the corresponding affinity equilibrium constants were determined. A shift of the peak potential on voltammograms accompanying formation of the boronate complex with FcBAwas proposed as a probe for electrochemical characterization of surface-confined diol-containing structures. The model experiments were carried out using sorbitol- and 1,6-hexandiol-modified polyepichlorhydrin conjugates deposited on the electrodes; theformer compound was able to form the boronate complex while no change of the peak potential for the latter conjugate was observed.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CE - Biochemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Electrochimica Acta

ISSN

0013-4686

e-ISSN

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Svazek periodika

56

Číslo periodika v rámci svazku

27

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

7

Strana od-do

10246-10252

Kód UT WoS článku

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EID výsledku v databázi Scopus

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