Rate Acceleration of the Heterogeneous Reaction of Ozone with a Model Alkene at the Air-Ice Interface at Low Temperatures

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F13%3A00066641" target="_blank" >RIV/00216224:14310/13:00066641 - isvavai.cz</a>

Výsledek na webu

<a href="http://pubs.acs.org/doi/abs/10.1021/es304812t" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/es304812t</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/es304812t" target="_blank" >10.1021/es304812t</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Rate Acceleration of the Heterogeneous Reaction of Ozone with a Model Alkene at the Air-Ice Interface at Low Temperatures

Popis výsledku v původním jazyce

The kinetics of the ozonation reaction of 1,1-diphenylethylene (DPE) on the surface of ice grains (also called "artificial snow"), produced by shock-freezing of DPE aqueous solutions or DPE vapor-deposition on pure ice grains, was studied in the temperature range of 268 to 188 K. A remarkable and unexpected increase in the apparent ozonation rates with decreasing temperature was evaluated using the Langmuir-Hinshelwood and Eley-Rideal kinetic models, and by estimating the apparent specific surface areaof the ice grains. We suggest that an increase of the number of surface reactive sites, and possibly higher ozone uptake coefficients are responsible for the apparent rate acceleration of DPE zonation at the air ice interface at lower temperatures. The increasing number of reactive sites is probably related to the fact that organic molecules are displaced more to the top of a disordered interface (or quasi liquid) layer on the ice surface, which makes them more accessible to the gas phas

Název v anglickém jazyce

Rate Acceleration of the Heterogeneous Reaction of Ozone with a Model Alkene at the Air-Ice Interface at Low Temperatures

Popis výsledku anglicky

The kinetics of the ozonation reaction of 1,1-diphenylethylene (DPE) on the surface of ice grains (also called "artificial snow"), produced by shock-freezing of DPE aqueous solutions or DPE vapor-deposition on pure ice grains, was studied in the temperature range of 268 to 188 K. A remarkable and unexpected increase in the apparent ozonation rates with decreasing temperature was evaluated using the Langmuir-Hinshelwood and Eley-Rideal kinetic models, and by estimating the apparent specific surface areaof the ice grains. We suggest that an increase of the number of surface reactive sites, and possibly higher ozone uptake coefficients are responsible for the apparent rate acceleration of DPE zonation at the air ice interface at lower temperatures. The increasing number of reactive sites is probably related to the fact that organic molecules are displaced more to the top of a disordered interface (or quasi liquid) layer on the ice surface, which makes them more accessible to the gas phas

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Environmental Science and Technology

ISSN

0013-936X

e-ISSN

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Svazek periodika

47

Číslo periodika v rámci svazku

13

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

6773-6780

Kód UT WoS článku

000321521400009

EID výsledku v databázi Scopus

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