X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F14%3A00075889" target="_blank" >RIV/00216224:14310/14:00075889 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1515/zkri-2014-1736" target="_blank" >http://dx.doi.org/10.1515/zkri-2014-1736</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1515/zkri-2014-1736" target="_blank" >10.1515/zkri-2014-1736</a>

Jazyk výsledku

angličtina

Název v původním jazyce

X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands

Popis výsledku v původním jazyce

The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N?N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N?N)] compounds, also ionic-type complexes having the formula of [Zn(N?N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi?pi stacking interactions and/or C?HxxxS non-covalent contacts

Název v anglickém jazyce

X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands

Popis výsledku anglicky

The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N?N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N?N)] compounds, also ionic-type complexes having the formula of [Zn(N?N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi?pi stacking interactions and/or C?HxxxS non-covalent contacts

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Zeitschrift für Kristallographie - Crystalline Materials

ISSN

0044-2968

e-ISSN

—

Svazek periodika

229

Číslo periodika v rámci svazku

7

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

6

Strana od-do

537-542

Kód UT WoS článku

000340864000007

EID výsledku v databázi Scopus

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