On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00082257" target="_blank" >RIV/00216224:14310/15:00082257 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.sciencedirect.com/science/article/pii/S0277538714005440" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0277538714005440</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2014.08.022" target="_blank" >10.1016/j.poly.2014.08.022</a>

Jazyk výsledku

angličtina

Název v původním jazyce

On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives

Popis výsledku v původním jazyce

In connection with our previous research, reactions of chlorodithiophosphoric acid pyridiniumbetaine, py.PS2Cl (I), with monoaryl thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = phenyl, 4-nitrophenyl) were studied with the aim to prepare new heterocyclic compounds. All reactions were carried out in acetonitrile in the presence of pyridine as an HCl acceptor. New compounds, pyridinium salts of 4-phenyl-3-sulfido-3,5-dithioxo-1,2,4,3k5-triazaphospholidine (II) and 4-(4-nitrophenyl)-3-sulfido-3, 5-dithioxo-1,2,4,3k5-triazaphospholidine (III) were prepared. 31P NMR, FT-IR, Raman spectroscopy, and X-ray diffraction analysis revealed their molecular structures consisting of pyridinium cation and fivemembered P?N?N?C?N heterocyclic anion bearing relevantaryl group.

Název v anglickém jazyce

On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives

Popis výsledku anglicky

In connection with our previous research, reactions of chlorodithiophosphoric acid pyridiniumbetaine, py.PS2Cl (I), with monoaryl thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = phenyl, 4-nitrophenyl) were studied with the aim to prepare new heterocyclic compounds. All reactions were carried out in acetonitrile in the presence of pyridine as an HCl acceptor. New compounds, pyridinium salts of 4-phenyl-3-sulfido-3,5-dithioxo-1,2,4,3k5-triazaphospholidine (II) and 4-(4-nitrophenyl)-3-sulfido-3, 5-dithioxo-1,2,4,3k5-triazaphospholidine (III) were prepared. 31P NMR, FT-IR, Raman spectroscopy, and X-ray diffraction analysis revealed their molecular structures consisting of pyridinium cation and fivemembered P?N?N?C?N heterocyclic anion bearing relevantaryl group.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polyhedron

ISSN

0277-5387

e-ISSN

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Svazek periodika

85

Číslo periodika v rámci svazku

January

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

4

Strana od-do

161-164

Kód UT WoS článku

000347582900022

EID výsledku v databázi Scopus

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