Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00083294" target="_blank" >RIV/00216224:14310/15:00083294 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity

Popis výsledku v původním jazyce

In our work, we synthetized two novel heteroleptic alkoxidic compounds, containing tin (IV) coordinated with N,O?B?heteroarylalkenolato ligands, Sn(4,5?Me?OxCHCOCF3)2(OtBu)2 and Sn(2?PyCHCOCF3)2(OtBu)2: Those compounds were fully structurally characterized and their properties and reactivity towards water and fluorination agents were investigated. Obtained results were compared with homoleptic tin (II) N,O?B?heteroarylalkenolato complexes already published in literature, Sn(4,5?Me?OxCHCOCF3)2 and Sn(2?PyCHCOCF3)2.

Název v anglickém jazyce

Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity

Popis výsledku anglicky

In our work, we synthetized two novel heteroleptic alkoxidic compounds, containing tin (IV) coordinated with N,O?B?heteroarylalkenolato ligands, Sn(4,5?Me?OxCHCOCF3)2(OtBu)2 and Sn(2?PyCHCOCF3)2(OtBu)2: Those compounds were fully structurally characterized and their properties and reactivity towards water and fluorination agents were investigated. Obtained results were compared with homoleptic tin (II) N,O?B?heteroarylalkenolato complexes already published in literature, Sn(4,5?Me?OxCHCOCF3)2 and Sn(2?PyCHCOCF3)2.

Druh

O - Ostatní výsledky

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/ED1.1.00%2F02.0068" target="_blank" >ED1.1.00/02.0068: CEITEC - central european institute of technology</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů