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Hakite from Pribram, Czech Republic: compositional variability, crystal structure and the role in Se mineralization

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F16%3A00111298" target="_blank" >RIV/00216224:14310/16:00111298 - isvavai.cz</a>

  • Nalezeny alternativní kódy

    RIV/68378271:_____/16:00467741 RIV/00023272:_____/16:N0000227 RIV/00216208:11310/16:10332769

  • Výsledek na webu

    <a href="https://www.cambridge.org/core/services/aop-cambridge-core/content/view/688020D62BFD8533C201A6FF683B5077/S0026461X00002632a.pdf/hakite_from_pribram_czech_republic_compositional_variability_crystal_structure_and_the_role_in_se_mineralization.pdf" target="_blank" >https://www.cambridge.org/core/services/aop-cambridge-core/content/view/688020D62BFD8533C201A6FF683B5077/S0026461X00002632a.pdf/hakite_from_pribram_czech_republic_compositional_variability_crystal_structure_and_the_role_in_se_mineralization.pdf</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1180/minmag.2016.080.038" target="_blank" >10.1180/minmag.2016.080.038</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Hakite from Pribram, Czech Republic: compositional variability, crystal structure and the role in Se mineralization

  • Popis výsledku v původním jazyce

    Hakite, ideally Cu10Hg2Sb4Se13, is a Se-dominant member of the tetrahedrite group occurring at only a few localities in the World. A new occurrence of this mineral in the Pribram uranium and base-metal ore district, Central Bohemia, Czech Republic, is reported in this paper. Hakite was found to be locally abundant and was identified in several samples with Se mineralization. Three chemically distinct types of hakite were distinguished based on electron microprobe study, Hg-rich hakite (hakite sensu stricto), Zn-rich hakite and Cd-rich hakite. Hg-hakite dominates among the samples studied. Its average empirical formula based on 29 apfu (n = 54) is (Cu5.61Ag0.39)(Sigma 6.00)Cu-4.00(Hg1.61Zn0.20Cu0.19Cd0.15Fe0.04)(Sigma 2.19) (Sb3.85As0.28)(Sigma 4.13)(Se11.55S1.14)(Sigma 12.69). Less common is the Zn-hakite, (Cu-5.80 Ag-0.20)(Sigma 6.00)Cu-4.00(Zn1.33Hg0.42Cd0.22Cu0.18Fe0.01)(Sigma 2.16)(Sb-3.85 As-0.26)(Sigma 4.11)(Se10.92S1.81)(Sigma 12.73) (n = 22), and rare Cd-hakite has an empirical formula (n = 7) of (Cu-5.84 Ag-0.16)(Sigma 6.00)Cu-4.00(Cd1.27Zn0.60Cu0.10Hg0.07Fe0.02)(Sigma 2.06)(Sb4.00As0.19)(Sigma 4.19)(Se12.14S0.61)(Sigma 12.75). The refined unit cell of Hg-hakite from Pribram, obtained from powder X-ray diffraction data, is a = 10.8783(3) angstrom with V = 1287.3(1)angstrom(3) (Z = 4, for the cubic space group I(4) over bar 3m). Structure refinement from the precession electron diffraction data collected on the transmission electron microscope (R = 24.4% for 424 observed reflections), confirmed that hakite is isostructural with tetrahedrite. The evolution of hydrothermal fluids, from which Se mineralization formed, suggests a distinct enrichment in sulfur and depletion in selenium over the time span of crystallization.

  • Název v anglickém jazyce

    Hakite from Pribram, Czech Republic: compositional variability, crystal structure and the role in Se mineralization

  • Popis výsledku anglicky

    Hakite, ideally Cu10Hg2Sb4Se13, is a Se-dominant member of the tetrahedrite group occurring at only a few localities in the World. A new occurrence of this mineral in the Pribram uranium and base-metal ore district, Central Bohemia, Czech Republic, is reported in this paper. Hakite was found to be locally abundant and was identified in several samples with Se mineralization. Three chemically distinct types of hakite were distinguished based on electron microprobe study, Hg-rich hakite (hakite sensu stricto), Zn-rich hakite and Cd-rich hakite. Hg-hakite dominates among the samples studied. Its average empirical formula based on 29 apfu (n = 54) is (Cu5.61Ag0.39)(Sigma 6.00)Cu-4.00(Hg1.61Zn0.20Cu0.19Cd0.15Fe0.04)(Sigma 2.19) (Sb3.85As0.28)(Sigma 4.13)(Se11.55S1.14)(Sigma 12.69). Less common is the Zn-hakite, (Cu-5.80 Ag-0.20)(Sigma 6.00)Cu-4.00(Zn1.33Hg0.42Cd0.22Cu0.18Fe0.01)(Sigma 2.16)(Sb-3.85 As-0.26)(Sigma 4.11)(Se10.92S1.81)(Sigma 12.73) (n = 22), and rare Cd-hakite has an empirical formula (n = 7) of (Cu-5.84 Ag-0.16)(Sigma 6.00)Cu-4.00(Cd1.27Zn0.60Cu0.10Hg0.07Fe0.02)(Sigma 2.06)(Sb4.00As0.19)(Sigma 4.19)(Se12.14S0.61)(Sigma 12.75). The refined unit cell of Hg-hakite from Pribram, obtained from powder X-ray diffraction data, is a = 10.8783(3) angstrom with V = 1287.3(1)angstrom(3) (Z = 4, for the cubic space group I(4) over bar 3m). Structure refinement from the precession electron diffraction data collected on the transmission electron microscope (R = 24.4% for 424 observed reflections), confirmed that hakite is isostructural with tetrahedrite. The evolution of hydrothermal fluids, from which Se mineralization formed, suggests a distinct enrichment in sulfur and depletion in selenium over the time span of crystallization.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10504 - Mineralogy

Návaznosti výsledku

  • Projekt

  • Návaznosti

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Ostatní

  • Rok uplatnění

    2016

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Mineralogical Magazine

  • ISSN

    0026-461X

  • e-ISSN

    1471-8022

  • Svazek periodika

    80

  • Číslo periodika v rámci svazku

    6

  • Stát vydavatele periodika

    GB - Spojené království Velké Británie a Severního Irska

  • Počet stran výsledku

    14

  • Strana od-do

    1115-1128

  • Kód UT WoS článku

    000391201100016

  • EID výsledku v databázi Scopus

    2-s2.0-84999287150