Fluorescence measurement of atomic oxygen concentration in a dielectric barrier discharge

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F17%3A00094851" target="_blank" >RIV/00216224:14310/17:00094851 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1088/1361-6595/aa70da" target="_blank" >http://dx.doi.org/10.1088/1361-6595/aa70da</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1088/1361-6595/aa70da" target="_blank" >10.1088/1361-6595/aa70da</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Fluorescence measurement of atomic oxygen concentration in a dielectric barrier discharge

Popis výsledku v původním jazyce

Concentration of atomic oxygen was measured in a volume dielectric barrier discharge (DBD) ignited in mixtures of Ar + O2 (+ H2) at atmospheric pressure. Two-photon absorption laser induced fluorescence (TALIF) of atomic oxygen was used and this method was calibrated by TALIF of Xe in a mixture of argon and a trace of xenon. The calibration was performed at atmospheric pressure and it was shown that quenching by three-body collisions has negligible effect on the life time of excited Xe atoms. The concentration of atomic oxygen in the DBD was around 10^{21} m-3 and it was stable during the whole discharge period. The concentration did not depend much on the electric power delivered to the discharge provided that the power was sufficiently high so that the visible discharge filled the whole reactor volume. Both the addition of hydrogen or replacing of argon by helium led to a significant decrease of atomic oxygen concentration. The TALIF measurements of O concentration levels in the DBD plasma performed in this work are made use of e.g. in the field analytical chemistry. The results contribute to understanding the processes of analyte hydride preconcentration and subsequent atomization in the field of trace element analysis where DBD plasma atomizers are employed.

Název v anglickém jazyce

Fluorescence measurement of atomic oxygen concentration in a dielectric barrier discharge

Popis výsledku anglicky

Concentration of atomic oxygen was measured in a volume dielectric barrier discharge (DBD) ignited in mixtures of Ar + O2 (+ H2) at atmospheric pressure. Two-photon absorption laser induced fluorescence (TALIF) of atomic oxygen was used and this method was calibrated by TALIF of Xe in a mixture of argon and a trace of xenon. The calibration was performed at atmospheric pressure and it was shown that quenching by three-body collisions has negligible effect on the life time of excited Xe atoms. The concentration of atomic oxygen in the DBD was around 10^{21} m-3 and it was stable during the whole discharge period. The concentration did not depend much on the electric power delivered to the discharge provided that the power was sufficiently high so that the visible discharge filled the whole reactor volume. Both the addition of hydrogen or replacing of argon by helium led to a significant decrease of atomic oxygen concentration. The TALIF measurements of O concentration levels in the DBD plasma performed in this work are made use of e.g. in the field analytical chemistry. The results contribute to understanding the processes of analyte hydride preconcentration and subsequent atomization in the field of trace element analysis where DBD plasma atomizers are employed.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10305 - Fluids and plasma physics (including surface physics)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Plasma Sources Science and Technology

ISSN

0963-0252

e-ISSN

—

Svazek periodika

26

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

—

Kód UT WoS článku

000403309700002

EID výsledku v databázi Scopus

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