Vše

Co hledáte?

Vše
Projekty
Výsledky výzkumu
Subjekty

Rychlé hledání

  • Projekty podpořené TA ČR
  • Významné projekty
  • Projekty s nejvyšší státní podporou
  • Aktuálně běžící projekty

Chytré vyhledávání

  • Takto najdu konkrétní +slovo
  • Takto z výsledků -slovo zcela vynechám
  • “Takto můžu najít celou frázi”

Insights into natural organic matter and pesticide characterisation and distribution in the Rhone River

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F17%3A00100130" target="_blank" >RIV/00216224:14310/17:00100130 - isvavai.cz</a>

  • Výsledek na webu

    <a href="http://www.publish.csiro.au/en/EN16038" target="_blank" >http://www.publish.csiro.au/en/EN16038</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1071/EN16038" target="_blank" >10.1071/EN16038</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Insights into natural organic matter and pesticide characterisation and distribution in the Rhone River

  • Popis výsledku v původním jazyce

    Thorough characterisation of natural organic matter (NOM) in natural surface waters remains vital for evaluating pollutant dynamics and interactions with NOM under realistic environmental conditions. Here, we present the characterisation of NOM and pesticide compositions for nine sampling sites over the length of the Rhone River, also evaluating the advantages and limitations of different analytical techniques to determine how they complement one another. Together with dissolved and particulate organic carbon analyses, the dissolved organic matter (DOM, &lt;0.8 mu m) or NOM (unfiltered organic matter) was characterised with gel permeation chromatography, the polarity rapid-assessment method, excitation-emission matrix fluorescence, and pyrolysis-gas chromatography-mass spectrometry to evaluate both composition and distribution. An additional objective was the determination of the NOM degradation state (i.e. constantly produced autochthonous or weakly degraded allochthonous species), an important factor in assessing potential NOM-pollutant interactions. The NOM compositions (i.e. proteins, polyhydroxy aromatics, polysaccharides, amino sugars) and proportions were similar between sites, but variations were observed in the relative proportions of autochthonous and allochthonous material from north to south. Anionic proteins and polyhydroxy aromatics in a molecular weight range of similar to 1000-1200 Da comprised the majority of the DOM. As a pollutant case study, five pesticides (glyphosate, metalochlor, chlortoluron, isoproturon, propyzamide) and some of their metabolites (aminomethylphosphonic acid, metolachlor ethanesulfonic acid and metolachlor oxanilic acid) were measured. Several exhibited trends with the NOM, particulate organic carbon and suspended particulate matter distributions in the Rhone waters, suggesting a significant influence on pesticide fate and transport in the river.

  • Název v anglickém jazyce

    Insights into natural organic matter and pesticide characterisation and distribution in the Rhone River

  • Popis výsledku anglicky

    Thorough characterisation of natural organic matter (NOM) in natural surface waters remains vital for evaluating pollutant dynamics and interactions with NOM under realistic environmental conditions. Here, we present the characterisation of NOM and pesticide compositions for nine sampling sites over the length of the Rhone River, also evaluating the advantages and limitations of different analytical techniques to determine how they complement one another. Together with dissolved and particulate organic carbon analyses, the dissolved organic matter (DOM, &lt;0.8 mu m) or NOM (unfiltered organic matter) was characterised with gel permeation chromatography, the polarity rapid-assessment method, excitation-emission matrix fluorescence, and pyrolysis-gas chromatography-mass spectrometry to evaluate both composition and distribution. An additional objective was the determination of the NOM degradation state (i.e. constantly produced autochthonous or weakly degraded allochthonous species), an important factor in assessing potential NOM-pollutant interactions. The NOM compositions (i.e. proteins, polyhydroxy aromatics, polysaccharides, amino sugars) and proportions were similar between sites, but variations were observed in the relative proportions of autochthonous and allochthonous material from north to south. Anionic proteins and polyhydroxy aromatics in a molecular weight range of similar to 1000-1200 Da comprised the majority of the DOM. As a pollutant case study, five pesticides (glyphosate, metalochlor, chlortoluron, isoproturon, propyzamide) and some of their metabolites (aminomethylphosphonic acid, metolachlor ethanesulfonic acid and metolachlor oxanilic acid) were measured. Several exhibited trends with the NOM, particulate organic carbon and suspended particulate matter distributions in the Rhone waters, suggesting a significant influence on pesticide fate and transport in the river.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10406 - Analytical chemistry

Návaznosti výsledku

  • Projekt

  • Návaznosti

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Ostatní

  • Rok uplatnění

    2017

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Environmental Chemistry

  • ISSN

    1448-2517

  • e-ISSN

    1449-8979

  • Svazek periodika

    14

  • Číslo periodika v rámci svazku

    1

  • Stát vydavatele periodika

    AU - Austrálie

  • Počet stran výsledku

    10

  • Strana od-do

    64-73

  • Kód UT WoS článku

    000392205800008

  • EID výsledku v databázi Scopus

    2-s2.0-85008871238