Ultraviolet photocatalytic degradation of cholesterol on TiO2: secondary ion mass spectrometry
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F17%3A00112484" target="_blank" >RIV/00216224:14310/17:00112484 - isvavai.cz</a>
Výsledek na webu
<a href="https://onlinelibrary.wiley.com/doi/pdf/10.1002/sia.6129" target="_blank" >https://onlinelibrary.wiley.com/doi/pdf/10.1002/sia.6129</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/sia.6129" target="_blank" >10.1002/sia.6129</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Ultraviolet photocatalytic degradation of cholesterol on TiO2: secondary ion mass spectrometry
Popis výsledku v původním jazyce
Cholesterol (C27H46O stated as M) is used as a model of bio-organic contamination, because this compound is in almost every living organism, and its photocatalytic degradation on titanium oxide (TiO2) surface with UV exposure is investigated. Secondary ion mass spectrometry as a surface-sensitive technique is suited to study this degradation process with focus on intermediates. A fragment of M-OH represents the intact molecule of cholesterol and provides its relative concentration on the surface. The intensity of M-OH decreases after 24-h UV irradiation, and the level of degradation is 89% with the pseudo-first kinetic constant of 0.0207min(-1) within 2h. A fragment of MO-H represents an intermediate as one of the cholesterol oxidation products. The irradiation from a bottom in comparison with a top reveals the differences in the mechanism of the intermediate formation through the intensity and the kinetics with values of factor of 1/3 and 30min, respectively. The roles of electrons and holes, primarily generated in TiO2 by UV, and also of superoxide anion radical and hydroxyl radical, as the secondary reactive species, are discussed to illustrate the bottom/top mechanisms.
Název v anglickém jazyce
Ultraviolet photocatalytic degradation of cholesterol on TiO2: secondary ion mass spectrometry
Popis výsledku anglicky
Cholesterol (C27H46O stated as M) is used as a model of bio-organic contamination, because this compound is in almost every living organism, and its photocatalytic degradation on titanium oxide (TiO2) surface with UV exposure is investigated. Secondary ion mass spectrometry as a surface-sensitive technique is suited to study this degradation process with focus on intermediates. A fragment of M-OH represents the intact molecule of cholesterol and provides its relative concentration on the surface. The intensity of M-OH decreases after 24-h UV irradiation, and the level of degradation is 89% with the pseudo-first kinetic constant of 0.0207min(-1) within 2h. A fragment of MO-H represents an intermediate as one of the cholesterol oxidation products. The irradiation from a bottom in comparison with a top reveals the differences in the mechanism of the intermediate formation through the intensity and the kinetics with values of factor of 1/3 and 30min, respectively. The roles of electrons and holes, primarily generated in TiO2 by UV, and also of superoxide anion radical and hydroxyl radical, as the secondary reactive species, are discussed to illustrate the bottom/top mechanisms.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10403 - Physical chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Surface and Interface Analysis
ISSN
0142-2421
e-ISSN
1096-9918
Svazek periodika
49
Číslo periodika v rámci svazku
4
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
6
Strana od-do
278-283
Kód UT WoS článku
000397496800006
EID výsledku v databázi Scopus
2-s2.0-84981742475